GCMS surrogates report for sample AE04513, Apr 2002

NYC 9/11 Public Portal Document

Data File : C:\MSDCHEM\l\DATA\032602\4513.D Vial: 58 , Acg On : 27 Mar 2002 8:51 pm Operator: McLean Sample : SAMPLE 4513 3/2/02 Inst Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\l\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Library : C:\DATABASE\WILEY7N.L

Peak Number 1 3-(CYCLOHEX-3'-EN-YL)PROPAN... Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

5.58 0.69 ug/L 199871 1,4-Dichlorobenzene-d4 9.55

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$... 174 C8H14O4 015745 37-6 28 2 Acetic acid, 3-[1,3]dioxolan-2-y... 174 C8H14O4 000000-00-0 28 3 1,3-Dioxolane, 2-(1-methylpropyl.. . 130 C7H14O2 014447-25-7 9 4 Octanal, 7-methoxy-3,7-dimethyl-... 186 C11H22O2 _____ 003613-30-7 9 Abundance Scan 426 (5.582 min): 4513.D (-) m/z 73.10 100.00% 73

5000 43 TTTT — I 55 5.20 5.40 5.60 5.80 6.00 ! | 103 0 ‘I’T hl 11 ,'........85 ' ■ i ■''' i ■ ‘111 >> >■ । । . f11»111■ 111■ 11,।> 11ij11> 11»1111> । m/z 43.20 32.74%| m/z-> 20 30 40 50 60 70 8C 90 100 110 120 130 140 150 160 170 180 Abundance#36138: 3-(CYCLOHEX-3‘-EN-YL)PROPANOL SS 2-Cyclohexene-1-p... 73

5000 V i ' r AMlyndyas ! r -MAA, MA 5.20 5.40 5.60 5.80 6.00 | 43 m/z 45.10 13.69%)

..... 55 ,i, 87 113 131 174 0 -T-tT-rTTj-rrT, 111" TTTT 111111111000001—011—0000— m/z-> 20 30 40 50 60 70 80 90 100 110120130140150 160170180 Abundance #78238: Acetic acid, 3-[1,3]dioxolan-2-ylpropyl ester 73 — 1 i ' 1 5.20 5.40 5.60 5.80 6.00 5000 m/z 41.20 12.38%|

43 27 55 >■1 01rrp-r TTET0"EEII , 87 —TETOUTEITETu 113 131 174 TTTTJCu m/z-> 20 30 40 50 60 70 80 90 100 110120 130 140150 160 170 180 Abundance #26623: 1,3-Dioxolane, 2-(1-methylpropyl)- $$ 1,3-Dioxolan... 73 IDHADMAALALMHIALA, 5.20 5.40 5.60 5.80 6.00 m/z 71.10 7.06%

5000

45 29 ) 57 . , 1 85 10° 129 m/z-> 0 TTTTTTTTTTT 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170180 ........—....... I I 5.20 5.40 5.60 5.80 6.00 |

1513.D 5080302.M Thu Mar 28 06:23:09 2002 Page 3

NYC-WTC_000038719