GCMS surrogates report for sample AE04511, Apr 2002

NYC 9/11 Public Portal Document ******

Data File : C:\MSDCHEM\1\DATA\032602\4511.D Vial: 56 • Acq On : 27 Mar 2002 7:13 pm Operator: McLean Sample : SAMPLE 4511 3/2/02 Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Library : C:\DATABASE\WILEY7N.L

Peak Number 1 Acetic acid, 3-[1,3]dioxola... Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

5.58 0.58 ug/L 173602 1,4-Dichlorobenzene-d4 9.55

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Acetic acid, 3-[1,3]dioxolan-2-y... 174 C8H14O4 000000-00-0 36 2 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$... 174 C8H14O4 015745-87-6 36 3 3-Pentanol, 3-methyl- 102 C6H140 000077-74-7 33 4 2-Hydroxy-2-methylbutanoic acid 118 C5H10O3 000000-00-0 28 Abundance Scan 426 (5.582 min): 4511.D (-) m/z 73.10 100.00% 73

5000 43 1 i ' 1 ‘ 1 i 1 ‘ TTTTTTTT 5.20 5.40 5.60 5.80 6.00 0 ■ 1 i 1 ■ ill 57 11|| , 87 103.. ........ ■ ' T1 171 i 11' ' i ' ' ' ' i ' ' ' ■ I 1 1 1 1 I ' 1 1 ' 1 1 1 ' 1 1 1 m/z 43.10 34.98% m/z-> 20 40 60 80 100 120 140 160 180 Abundance #78238: Acetic acid. 3-[1,3]dioxolan-2-ylpropyl ester 73

5000 —r T—4 AAA 5.20 5.40 5.60 5.80 6.00 43 m/z 45.10 13.65%

27 55 1, 87 113 131 174 0 ' 1 ‘ 1 T • ■ i ■ 1 ■ ■ i ■ ■ 1 ' i ' ■ ' ■ i 1 1 1 ' 1 1 1 1'1 1 1 ■ ■ i > • m/z-> 20 40 60 80 100 120 140 160 180 Abundance#36138: 3-(CYCLOHEX-3’-EN-YL)PROPANOL $S2-Cyclohexene-1-p... 73 1 —4... 5.20 5.40 5.60 5.80 6.00 5000 m/z 41.20 12.08%

43

m/z-> 0 27 55 ■ • i................ I । । । । I । 1 20 40 60 80 487100 113 131 120 140 160 174 180 Abundance #9663: 3-Pentanol, 3-methyl- 73 5.20 5.40 5.60 5.80 6.00 m/z 71.10 7.76%

5000

55 45 87 27

m/z-> 0 15,20 l—40ll 1 60 .,1 80 100 ...A 120 140 160 180 TIP 5.20 5.40 5.60 5.80 6.00 1’111111

1511.D 5080302.M Thu Mar 28 06:20:01 2002 Page 3

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