GCMS analysis results for sample AE03181, March 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\031802\3181.D Vial: 13 Acq On : 19 Mar 2002 12:00 pm Operator: McLean Sample : GC/MS SCAN 3/6 Inst : Instrumen Mise Multipir: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Library : C:\DATABASE\WILEY7N.L

Peak Number 1 3-(CYCLOHEX-3’-EN-YL)PROPAN... Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T. 5.57 0.61 ug/L 147924 1,4-Dichlorobenzene-d4 9.54 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$... 174 C8H14O4 015745-87-6 9 2 Acetic acid, 3-[1,3]dioxolan-2-y... 174 C8H14O4 000000-00-0 9 3 3-Pentanol, 3-methyl- 102 C6H140 000077-74-7 9 4 1,3-Dioxolane (CAS) $$ 1,3-Dioxo... 74 C3H602 000646-06-0 5 Abundance Scan 275 (5.570 min): 3181.D (-) m/z 73.10 100.00% 73

5000

■ i •11 ■ i T T fAr 45 55 ............... I , hl . I11 11, 187 , । । , , , । । , , , , । , , , 5.20 5.40 5.60 5.80 6.00 m/z 45.10 13.92% 01 m/z-> • ■ i ■ ' ‘ • I ' ■ ■ ■ i ' ‘ 20 40 60 80 100 Abundance#36138: 3-(CYCLOHEX-3‘-EN-YL)PROPANOL $$ 2-Cyclohexene-1-p... 120 140 160 180 1 73

5000 5.20 5.40 5.60 5.80 6.00 43 m/z 55.10 7.68%

27 55 87 113 131 174 Of Ip—ppp*.! 1 I " । i । । »- miz-> 20 40 60 80 100 120 140 160 180 Abundance #78238: Acetic acid, 3-[1,3]dioxolan-2-yipropyl ester 73 ■ i • ■ ■ ■ i • • ■ ■ i ■7 ■ ■ i • • ■ • i ■ 5.20 5.40 5.60 5.80 6.00 5000 m/z 71.10 7.19%

43

m/z-> 01 •*1* 20 27 40 -55,4 lit.

60 87 1 1 1* 1 80 113 100 120 131 140 160 174 180 Abundance #9663:3-Pentanol, 3-methyl- 73 ’I T T T T 5.20 5.40 5.60 5.80 6.00 m/z59.10 6.58%

5000

55

0 -15 — 27 45 —t 87 T TT-p-m-p- miz—> 20 40 60 80" 180 ”120 140‘180 180 'I 1 1 1 1 I 5.20 5.40 5.60 5.80 6.00

3181.D 5080302.M Tue Mar 19 21:38:56 2002 Page 3

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