GCMS quantitation results for sample AE04029, March 2002

NYC 9/11 Public Portal Document LIbrary searen compound Keport

Data File : C:\HPCHEM\l\DATA\MAR2202\4029.D Vial: 35 Acq On : 24 Mar 2002 3:38 am Operator: Sample : gc/ms scan 2/25 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0308.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 3 Ethyl 3-aminocrotonate Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

21.09 0.23 ug/1 37074 Acenaphthene-dl0 21.21

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Ethyl 3 -aminocrotonate 129 C6H11NO2 000626-34-6 32 2 Cyclohexanone, 4- methyl - 112 C7H120 000589-92-4 18 3 Boranamine, ,1,1-tetraethyl- 141 C8H20BN 004023-39-6 16 4 Cyclohexene, methoxy- 112 C7H120 000931-57-7 16 Abundance z 55 Scan 1748 (21.095 min): 4029.D (-) m/ z 55.00 100.00%

84 5000 111 41 100 129 A m/z-> Abundance —PPPPT - 20 30 40 50 u - 71 141 ' I ' ' ---------- IITT 60 70 80 90 100 110 120 130 140 150 160 156 20.80 21.00 21.20 21.40 m/z "" 83.95 58.17% #5220: Ethyl 3-aminocrotonate 84 57 42 5000 129 MAAAAPMAA—LN 1 MAMMA 20.80 21.00 21.20 21.40 68 m/z 111.00 36.69% 27 1 i ■ ' ■ ' i ' 1....... 101 . 114...... i,..................... * ’ 11 •'1 I '1 " I' ’ *11 * ’ *' I ' 111 I 11 1 ‘ I 1 11 111 1 m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 Abundance 4 001 : o p. ■ ■ 55 1 ' I ' ' 1 ’ I T.TB 20.80 21.00 21.20 21.40 5000 27 m/z 129.00 32.32% 42 112 83 70 __________ _______ __________________ 97 miz-> 20 30 40 50 60 70 80 90 100 110 120 1 30 140 150 160 Abundance #66110: Boranamine, N,N,1,1-tetraethy- ILT 84 20.80 21.00 21.20 21.40 m/z 41.05 32.08% 112 5000-

54 70 - - 98 126 141 -....... - TTTPIPTPTT TTE m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 J 20.80 21.00 21.20 21.40

4029.D GCMS0308.M Tue Mar 26 10:43:03 2002 Page 3

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