GCMS analysis results for sample AD29522, Feb 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\5973N\02FEB01\29522.D Vial: 4 Acq On : 1 Feb 2002 1:04 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 1, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 3 3-Pentanol, 2,4-dimethyl- Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T. 5.92 0.46 ug/L 195775 1,4-Dichlorobenzene-d4 9.71

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-Pentanol, 2,4-dimethyl- 116 C7H160 000600-36-2 33 2 3-Pentanol, 2,4-dimethyl- 116 C7H160 000600-36-2 33 3 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$... 174 C8H14O4 015745-87-6 28 4 Acetic acid, 3-[1,3]dioxolan-2-y... 174 C8H14O4 000000-00-0 28 Abundance Scan 223 (5,920 min): 29522.D (-) m/z 73.10 100.00% 73

miz-> 5000

0- 43

—10..20304050607080 -45, —IIuBnma]] 11 87 103 90 100 110 120 130 140 150 160 170 180 L ■ 1 ‘ i ■ ■ ‘ ■ i • ■ ■ ■ i ' • ■ • i ■ ■ ■ ■ i

m/z 5.60 5.80 43.10 6.00 6.20 22.12% Abundance #17065: 3-Pentanol, 2,4-dimethyl- 73

5000 55 5.60 A 5.80 V 6.00 ' 6.20' ' ' 1 43 m/z 45.10 10.32% 27

miz—> 83 0- .......... Ji....... 11pur I “I0—atnemr 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #17063: 3-Pentanol, 2,4-dimethyl- 73 - 5.60 5.80 6.00 6.20 5000 m/z 41.10 8.67% 55 43 27 0-__ __15 , I |....I l | — I> I > r 1 . | I1 1 > | . I I 1 [ ’ I ‘ ■1 ■ I ■ • ■ ■ i ITT | | | .

A '’i‘ miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #36138:3-(CYCLOHEX-3'-EN-YL)PROPANOL $$ 2-Cyclohexene-1-p... T TI 73 5.60 5.80 6.00 6.20 m/z 71.10 6.16%

5000 43 27 0 Tm 55.... , Hp 87 ‘l1 ’ “ I•“ ‘1 113 < ‘TTTTT T! ■ > 11।।।। ।।. 174 miz—> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 5.60 5.80 6.00 6.20 1

29522.D SCAN508.M Mon Feb 04 08:41:11 2002 Page 5

NYC-WTC_000036787