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GCMS comments for sample AD29187, Jan 2002

Machine-extracted title · confidence 95%

Laboratory commentary noting low recovery and acidic pH for sample AD29187, recommending re-extraction and re-analysis on January 4, 2002.

NYC-WTC_000036513–000036529

Folder label: “GCMS X 12/6/01 A 12/12/01 - 12/13/01

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\HPCHEM\l\DATA\DEC1301\29187.D Vial 6 Acq On : 13 Dec 2001 2:44 pm Operator 209 GALOS Sample : gems scan 12/6 Inst GC/MS 209 Mise : Multiplr 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 9 Heneicosane Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

36.26 1.85 ug/1 434323 Perylene-dl2 37.10

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Heneicosane 296 C21H44 000629-94-7 91 2 Tetratetracontane 619 C44H90 007098-22-8 91 3 Hexatriacontane 507 C36H74 000630-06-8 91 4 Heneicosane, 11-(1-ethylpropyl)- 366 C26H54 055282-11-6 91 Abundance Scan 3400 (36.259 min): 29187.D (-) m/z 57.0.0 100.00% 57 i 5000 85 ________________________

miz-> 4113141 183210 239267 50 100 150 200 250 300 350 400 450 500 550 600 36.00 36.20 36.40 36.60 m/z 43.7 65.67% Abundance #42201: Heneicosane 57 | 85 5000 - I I 36.00 36.20 36.40 36.60 m/z 71.0 62.22% 113.

miz-> ' ■ I ' 50 100 L41 150 200 250 268296 300 350 400 450 500 550 600 Abundance #74745: Tetratetracontane 57 — . ■ ■ i ■ ■1 1 r1 36.00 36.20 36.40 36.60 5000 85 m/z 85.0.0 45.78%

_ 1113141....................................463491 519547,591618 m/z-> 50 100 150 200 250 300 350 400 450 500 550 600 'Abundance #59136: Hexatriacontane 57 36.00 36.20 36.40 36.60 m/z 41.00 24.42% 5000 85

— 113141 4i '■ 239 379407435 478506 m/z—> 50 100 150 200 250 300 350 400 450 500 550 600 | 36.00 36.20 36.40 36.60

29187.D GCMS1126.M Fri Dec 21 13:06:39 2001 Page 9

NYC-WTC_000036528

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NYC-WTC_000036528Source: NYC Law Department, mirrored locally

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