GCMS analysis comments for sample AD28689, Dec 2001

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C: \HPCHEM\ 1 \DATA\DEC04 0 1\28689.D Vial: 14 Acq On '5 Dec 2001 1:04 am Operator: 209 GALOS Sample gc/ms 11/24 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 2 Butyl hexadecanoate Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

29.44 5.79 ug/1 1139090 Chrysene-dl2 33.03

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Butyl hexadecanoate 312 C20H40O2 000000-00-0 35 2 1-Hexene, 2-methyl- 98 C7H14 006094-02-6 27 3 Cyclobutane, 1,l-dimethyl-2-octyl- 196 C14H28 062338-30-1 27 4 1,3-Hexanediol, 2-ethyl- 146 C8H18O2 000094-96-2 23 Abundance / “ ......... Scan 2657 (29.436 min): 28689.D (-) 56 m/ z 56.00 100.00%l

5000 41 73 257 .... — 1 1 l ■ '

—TT "t —JLA”l0‘116110143157171185199213..228 312 29.20 29.40 29.60 29.80 ; 1 283 TTI‘"t‘1uh TT m/z 57.00 48.88% miz-> 20 40 60__ 80 100 120 140 160 180 200 220 240 260 280 300 Abundance #44549: Butyl hexadecanoate 55

5000 258 312 W f TE"T 1 i 1 1 29.20 29.40 29.60 29.80 73 240 11612® m/z 41.0.5 40.42% | 101 | 157 171 185 p-TT-r-p-T-T! j TT-T-r-|-rT*TTT->-r^ 214 I 1 1 1 'I । ' ‘ | H TT m/z->__ 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 Abundance #1354: 1 -Hexene. 2-methyl- 56 -IP 41 29.20 29.40 29.60 29.80 5000 m/z 43.0.0 40.07 27

I' “ ' i'11 ■i ■ 78398........ miz-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 Abundance #21985: Cyclobutane, 1.1 -dimethyl-2-octyl- 56 29.20 29.40 29.60 29.80 m/z 73.00 31.31% I 5000

! 27 * ..... ........ TTT 70 83 97 111 125 140 168 196_______________ 7TTTT1 . TT p I I I I i t I 1 | H . . | . . t i | ■ ■ . . { > ■ ■ . | | I | . . . I | | M i I i > > i I ------- miz-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 29.20 29.40 29.60 29.80

28689.D GCMS1126.M Mon Dec 10 10:19:03 2001 Page 2

NYC-WTC_000035203