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GCMS analysis results for sample AD27986, Jan 2002

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Laboratory report documenting GCMS analysis of sample AD27986 conducted on January 2, 2002, noting unknown compounds and surrogate recovery.

NYC-WTC_000034472–000034483

Folder label: “GCMS X 11/21/01 A 12/21/01

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NYC 9/11 Public Portal Document Library Search Compound Report

Data File : C: \HPCHEM\ 1 \DATA\DEC1901\27986.D Vial: 27 Acq On : 21 Dec 2001 7:40 am Operator: GALOS Sample : gems unknown 11/21 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ************************************************************ * * ******* Peak Number 3 2-Undecene, 4,5-dimethyl-, [R@ Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

35.67 0.43 ng/uL 89659 Perylene-dl2 37.24

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 2-Undecene, 4 5-dimethyl-, [R@,S@-( 182 C13H26 055170-93-9 16 2 Methyl 4-(met oxycarbonylmethyl)dec 258 C14H2604 000000-00-0 12 3 Octane, 4-ethyl- 142 C10H22 015869-86-0 12 4 Propanedioic acid, hexyl-, diethyl 244 C13H2404;_______ 005398-10-7 12 Abundance Scan 3362 (35.675 min): 27986.D (-) m/z 185.10 100.00% 57 185

70 5000 43 112 83 98 281 35.40 35.60 35.80 36.00 1 : .... II 1 1 1 1 1 1 ' 1 I ' ' ' ' I ' ' I ■ ■ r■ | ' I ' • ■ ■ I ■ ■ ' ' I ■ ■ . . । 207 . f i | I . q . . . . । . . . . । . m/z 57.10 87.78% miz-? 20 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #18485:2-Undecene, 4,5-dimethyl-, [R@,S@-(Z)]- 57 69 43

5000 AA A4 , AAl , , MAQall 35.40 35.60 35.80 36.00 83 98 112 m/z 70.05 5 8.46% 140 : I ' ' 1 ' I ' 1 4 4 1 ... j..... 182.... miz- 20 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #3549: Methy 4 pcthoxycarbonylmethyl)decancate 185

35.40 35.60 35.80 36.00 153 5000 69 m/z 71.05 51.38% I 83 96 111 227 1 , 135 55 179— , 1_ m/z->20 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #8095: Octane, 4-ethyl- TII Illi l i 1 1 1 1 I ■ 1 57 35.40 35.60 35.80 36.00 m/ Z: 55.10 46.62% 5000 71

! 27 42 I ' ’ 1 ' r1 1 _ 60 II i ■ ■1 ■ i 80 85 98 112 +100 120 142 140 160 180 200 220 240 260 280 MM unM“rArowr 35.40 35.60 35.80 36.00

27986.D NP112701.M Fri Dec 28 09:31:52 2001 Page 3

NYC-WTC_000034482

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NYC-WTC_000034482Source: NYC Law Department, mirrored locally

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