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GCMS unknowns analysis results for sample AD28230, Jan 2002

Machine-extracted title · confidence 100%

Laboratory report documenting GCMS analysis for unknown compounds and surrogate recovery in sample AD28230 conducted on January 9, 2002.

NYC-WTC_000033965–000033973

Folder label: “GCMS X 11/20/01 A 11/26/01”

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\HPCHEM\1\DATA\NOV2601\28230.D Vial: 18 Acq On : 28 Nov 2001 10:52 am Operator: 209 GALOS Sample : 11/20 scan Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 l,4-Dichlorobenzene-d4 Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T. 11.56 0.53 ug/1 108042 1,4-Dichlorobenzene-d4 11.70 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1,4-Diehl orobenzene-d4 150 C6C12D4 003855-82-1 47 2 Benzene-l,2/3,4-d4-, 5,6-dichloro- 150 C6C12D4 002199-69-1 39 ( 3 Benzaldeh de, 2-hydroxy-3 -methoxy- 152 C8H803 000148-53-8 10 4 Benzaldeh de, 2-hydroxy-5-methoxy- 152 C8H803 _______ 000672-13-9 9 Abundance / Scan 710 (11.561 min): 28230.D (-) " ... 7 .......... m/z 149.90 100.00% 150

5000 115 52 78 87 | 11.20 1140 11.60 11.80 ' - 38 44 I --- 63 . 11 1.TT. n... i1-ITITTTTTTTT m/z 151.90 56.29% miz-> 30 40 50 60 70 80 ..90 100 110 120 130 140 150 160 Abundance #9593: 1,4-Dichlorobenzene-d4 150

5000 115 TT 78 11.20 11.40 11.60 11.80 52 m/z 114.90 32.67% 35 87 1 TTTTrru’TT '11111 IT TIPTTTT t TTTTTT ''1 I ' ' nz—> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 Abundance #1592: Bonzest-1.2,3.4-d4-, 5.6-dichloro- 150 —TIRTum——mmTTTT 115 11.20 11.40 11.60 11.80 5000 52 78 m/z 77.95 . 17.40%

35 87 ' I ' 1 ' 1 I ' ' 111 ' 11111111 TWPmTTPTTTT T’um’T—n—t—mourr miz-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 —........ - Abundance #66892: Benzaldehyde, 2-hydroxy-3-methoxy- TTTTTT 152 11.20 11.40 11.60 11.80 m/z 52.00 13.35% 106 5000 53 81

92 122 T-i-p-TTTrj-TT-r-rp — PPTTT 136 TTTIT’" " I" " I miz—> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 11.20 11.40 11.60 11.80

28230.D GCMS1126.M Thu Jan 03 12:47:09 2002 Page 1

NYC-WTC_000033972

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NYC-WTC_000033780

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GCMS comments for sample AD28325, Nov 2001 · Box DEP Box 21

NYC-WTC_000033816

Analytical commentary for sample AD28325 dated November 29, 2001, noting no unusual compounds but low recovery rates for LCS standards.

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