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GCMS comments for sample AD28149, Nov 2001

Machine-extracted title · confidence 100%

Analytical commentary for sample AD28149 dated November 29, 2001, noting no unusual compounds but low recovery rates for LCS standards.

NYC-WTC_000033765–000033779

Folder label: “GCMS X 11/20/01 A 11/26/01”

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\HPCHEM\1\DATA\NOV2601\28159.D Vial: 21 Acq On : 27 Nov 2001 6:15 am Operator: 209 GALOS Sample : 11/20 scan Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 3 Ethanedioic acid, bis(trimethy Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T. 38.03 1.16 ug/1 204160 Perylene-dl2 37.12 Hit# Of 5 Tentative ID MW MolForm CAS# Qual 1 Ethanedioic acid, bis(trimethylsily 234 C8H1804Si2 018294-04-7 35 2 Trisiloxane, 1/1,1,5,5,5-hexamethyl 384 C12H3604Si5i 003555-47-3 25 3 1,2-Bis (trimethylsiloxy) ethane 206 C8H2202Si2 007381-30-8 16 4 Cyclopropan line, N-methyl-l-phenyl 147 C10H13N 056771-48-3 12 Abundance / Scan 3593 (38.032 min): 28159.D (-) m/z; 72.95 100.00% 73 .................... ........... 147

5000 221 281 355 TTTTTTTTTTPI , .. 429 37.80 38.00 38.20 38.40 43 191 TITpo4 TTTTTTTTHTTTTT 1 .... । fta m.t T T 327 L 401TTT mm T T m/z 147.00 73.92% miz-> 40 60 80 100120140160180200220240260280300320340360380400420 Abundance #71006: Ethanedioic acid, bis(trimethylsilyl) ester 73

147 5000 37.80 38.00 38.20 38.40 45 m/z 221.05 46.54% ................. / | | 117.. . ................................ TTTTT TCTUu—gTTTTTT TT , T TCTICTETEITTETTT m-|-n i TITT"TTTEITTTT‘TT‘ m/z-> 40 60 80 100120140160180200220240260280300320340360380400420 Abundance #74103: Trisiloxane, 1,1,1,5,5,5-hexamethyl-3,3-bis[(trimet 73 147 TETEETIT _ 37.80 38.00 38.20 38.40 5000 m/z 207.00 30.76% 281 45 369 I , 117 207 249 . , HH| |, L p I 11 | H I 11 H H | I TT—TTTTTTTTTTT’ TTTTTTTTTTTTTTTTTTT T TT TTTTTTTTTTTTTT miz-> 40 60 80 100120140160180200220240260280300320340360380400420 Abundance #70005:1,2-Bis(trimethylsiloxy)ethane 147 37.80 38.00 38.20 38.40 m/z 281.00 26.79% 73 5000

103 191 47 47 ,| , 1 .,i | TTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTT Trrrrj-r 1 I I m/z—> 40 60 80 100120140160180200220240260280300320340360380400420 37.80 38.00 38.20 38.40

28159.D GCMS1126.M Wed NOV 28 11:15:54 2001 Page 3

NYC-WTC_000033774

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