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GCMS comments for sample AD28149, Nov 2001

Machine-extracted title · confidence 100%

Analytical commentary for sample AD28149 dated November 29, 2001, noting no unusual compounds but low recovery rates for LCS standards.

NYC-WTC_000033765–000033779

Folder label: “GCMS X 11/20/01 A 11/26/01”

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\HPCHEM\1\DATA\NOV2601\28159.D Vial: 21 Acq On : 27 NOV 2001 6:15 am Operator: 209 GALOS Sample : 11/20 scan Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 Trisiloxane, 1,1,1,5,5,5-hexam Concentration Rank 6 R.T. EstConc Area Relative to I STD R.T. 36.72 0.64 ug/1 112576 Perylene-d12 37.12 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Trisiloxane, 1, 1,1,5,5,5-hexamethyl 384 C12H3604Si5 003555-47-3 38 2 1,2-Benzenedicarboxylic acid, bis(t 310 C14H2204Si2 002078-22-0 16 3 Mercaptoacetic acid, bis(trimethyls 236 C8H20O2SSi2 006398-62-5 12 4 3-Isopropo; -1,1,1,7,7,7-hexamethyl 576 C18H5207Si7 071579-69-6 12 Abundance Z Scan 3450 (36.719 min): 28159.D (-) m/z 73.00 100.00% 73 147 5000 221 281 355

mlz-> 45 96 117 Tjm TTTMTTTTTTTTTTTT "TT „11.. Tpe , TTTTT TTTU - 327, 40 60 80 100120140160180200220240260280300320340360380400420 429 36.40 36.60 36.80 37.00 m/z 147.00 67.61% Abundance #74103: Trisiloxane, 1,1,1,5,5,5-hexamethyl-3,3-bis[(trimet 73 147

5000 —IrPTPtP 36.40 36.60 36.80 37.00 281 369 m/z 221.05 44.09% 45 207 | 117 117 _ —27 249. . _ 249 m/z-> 40 6080 100 120140160180 200 220240 260 280300 320 340 360380 400 420 ' Abundance #72972:1,2-Benzenedicarboxylic acid, bis(trimethylsily!) e 147 73 "CTTfmTr -A 36.40 36.60 36.80 37.00

1 5000

45 295

miz—> 119 , —193 221 I mmTTTTTTTTTTTITTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTT 40 60 80 100120140160180200220240260280300320340360380400420 WWW—VV Abundance #30949: Mercaptoacetic acid, bis(trimethylsily)- T T T T 73 36.40 36.60 36.80 37 00 147 m/z 354.95 20.80% 5000 221 45 104 193 TTTTT mhr TTTTTTTTTTTTTTTTTTTTTTTTT TT TTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTT T T T r m/z—>40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 420 36.40 36.60 36.80 37.00

28159.D GCMS1126.M Wed NOV 28 11:15:51 2001 Page 2

NYC-WTC_000033773

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