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GCMS calibration data for TCLP analysis dated December 7, 2001

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Instrument output file listing calibration standards and response factors for various compounds used in the December 7, 2001 analysis.

NYC-WTC_000031665–000031684

Folder label: “GCMS X 11/6/01 A 12/7/01

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NYC 9/11 Public Portal Document LSC Area Percent Report

• Data File C: \HPCHEM\ 1 \DATA\DECO 7 01 \LB. D Vial: 2 Acq On 7 Dec 2001 7:01 pm Operator: GALOS Sample gc/ms unknown 11/6 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Smoothing : OFF Filtering: 5 Sampling : 1 Min Area: 1 % of largest Peak Start Thrs: 0.2 Max Peaks: 100 Stop Thrs : 0 Peak Location: TOP

If leading or trailing edge < 100 prefer < Baseline drop else tangent > Peak separation: 5

Signal : TIC

peak R.T. first max last PK peak peak peak % of # min scan scan scan TY height area % max. total

1 4.995 11 17 24 rBV 191786 536306 6.94% 1.038% 2 5.0 7 24 27 31 rW 268274 545324 7.05% 1.055% 3 5.151 31 34 56 rVB 426276 1405927 18.18% 2.721% 4 5.582 77 81 84 rW 41922 91188 1.18% 0.176% 5 5.637 84 87 104 rVB 70358 238498 3.08% 0.462%

6 6.096 133 137 153 rBV 227418 765751 9.90% 1.482% 7 6.444 171 175 182 rBV 98449 234102 3.03% 0.453% 8 6.554 183 187 197 rW 96471 246248 3.18% 0.477% 9 6.683 197 201 210 rW 102292 237285 3.07% 0.459% 10 6.802 210 214 220 rW2 58448 122198 1.58% 0.237%

11 7.159 247 253 265 rBV 1717874 3667346 ( 47.42% 7.098% 12 7.829 322 326 345 rVB 1200939 2620468 33,89% 5.072% 13 9.342 487 491 500 rBV 62680 150415 1.95% 0.291% 14 10.314 592 597 607 rBV 464849 1005369 13.00% 1.946% 15 10.525 615 620 628 rBV 233508 485902 6.28% 0.940%

16 11.882 762 768 779 rBV 2982068 6200598 80.18% 12.001% 17 15.495 1156 1162 1179 rBV 3863556 7733013 100.00% 14.967% 18 20.768 1731 1737 1758 rBV 3808617 7703725 99.62% 14.911% 19 25.179 2211 2218 2229 rBV2 3365584 7224363 93.42% 13.983% 20 33.184 3084 3091 3105 rBV2 2552852 5755388 74.43% 11.140%

21 37.274 3529 3537 3557 rBV2 1715992 4696396 60.73% 9.090%

Sum of corrected areas: 51665810

LB.D NP112701.M Thu Dec 13 11:28:15 2001

NYC-WTC_000031669

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NYC-WTC_000031669Source: NYC Law Department, mirrored locally

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