GCMS calibration results for sample AE10851, May 2002

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\1\DATA\MAY15O2\CAL4O .D Vial: 2 Acq On 15 May 2002 9:34 am Operator: Sample Inst : 209 Mise : Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: May 15 15:28 2002 Quant Results File: GCMS0510.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0510.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed May 15 14:56:50 2002 Response via : Initial Calibration DataAcq Meth : GCMS0510

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.17 152 545440 40.00 ug/1 -0.03 10) Naphthalene-d8 15.80 136 2182000 40.00 ug/1 -0.04 17) Acenaphthene-diO 21.10 164 1036586 40.00 ug/1 -0.04 30) Phenanthrene-diO 25.55 188 1514391 40.00 ug/1 -0.03 38) Chrysene-dl2 33.62 240 998745 40.00 ug/1 -0.02 44) Perylene-dl2 37.84 264 559217 40.00 ug/1 -0.02

System Monitoring Compounds 28) TCMX 23.25 209 53757 10.43 ug/L -0.03 Spiked Amount 10.000 Recovery = 104.30%

Target Compounds 18 62 Qvalue 2) N-nitrosodimethylamine 5.82 74 656439 47.78 ug/1 88 3) bis(2-Chloroethyl)ether 11.56 93 907480 50.93 ug/1 100 4) 1,3-Dichlorobenzene 12.06 146 717999 42.48 ug/1 99 5) 1,4-Dichlorobenzene 12.20 146 790458 42.74 ug/1 99 6) 1,2-Dichlorobenzene 12.73 146 687573 42.72 ug/1 98 7) 2,2'-oxybis(1-Chloropropan 13.05 45 2046940 59.25 ug/1 97 8) N-Nitrosodi-n-propylamine 13.43 70 638330 50.14 ug/1 93 9) Hexachloroethane 13.57 117 343818 52.26 ug/1 87 11) Nitrobenzene 13.84 77 807849 45.60 ug/1 94 12) Is ophorone 14.49 82 1559086 44.90 ug/1 98 13) bis(2-Chloroethoxy)methane 15.18 93 1035878 46.05 ug/1 99 14) 1,2,4-Trichlorobenzene 15.69 180 563056 37.17 ug/1 99 15) Naphthalene 15.86 128 2035360 45.33 ug/1 99 16) Hexachlorobutadiene 16.40 225 272939 38.92 ug/1 99 18) Hexachlorocyclopentadiene 18.59 237 201544 38.37 ug/1 99 19) 2-Chloronaphthalene 19.36 162 954865 42.16 ug/1 97 20) Dimethylphthalate 20.46 163 1205464 42.27 ug/1 100 21) 2,6-Dinitrotoluene 20.67 165 270214 44.30 ug/1 # 90 22) Acenaphthylene 20.63 152 1706163 42.28 ug/1 99 23) Ac enaphthene 21.20 153 1045124 43.45 ug/1 100 24) 2,4-Dinitrotoluene 21.83 165 303177 46.12 ug/1 90 25) Diethylphthalate 22.60 149 1111321 43.52 ug/1 99 26) 4-Chlorophenylphenylether 22.74 204 563196 44.61 ug/1 98 27) Fluorene 22.72 166 1087449 42.87 ug/1 100 29) Azobenzene 23.21 77 1563673 49.46 ug/L 96 31) N-Nitrosodiphenylamine 23.14 168 430402 45.50 ug/1 92 32) 4-Bromophenylphenylether 24.21 248 308860 41.24 ug/1 99 3 3) Hexachlorobenzene 24.64 284 328487 38.39 ug/1 # 93 3 4) Phenanthrene 25.62 178 1488408 40.96 ug/1 100

(#) = qualifier out of range (m) = manual integration CAL40.D GCMS0510.M Wed May 15 15:28:54 2002 Page 1

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