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GCMS analysis with surrogate recovery, sample AE10895, May 2002

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Gas chromatography-mass spectrometry analysis of sample AE10895 with 91% surrogate recovery for 2,4-DDD, conducted May 21, 2002.

NYC-WTC_000024070–000024082

Folder label: “GCMS X 5/10/02 A 5/16/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\051602\10895.D Vial: 8 Acq On : 16 May 2002 8:14 pm Operator: Mclean Sample : 5/10 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 3 2-Propenal, 3-(3,4-dimethox... Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T.

22.58 0.27 ug/L 241496 Phenant hranene-dl0 22.95

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 2-Propenal, 3-(3,4-dimethoxyphen... 192 C11H1203 004497-40-9 42 0/ 2 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 40' 3 Isoquinoline, 1,2,3,4-tetrahydro... 328 C18H20N2O4 1000128-79-2 38 4 Anthracene, 2-methyl- 192 C15H12 000613-12-7 36 Abundance Scan 3319 (22.580 min): 10895.D (-3309) (-) m/z 192.10 100.00% 192

5000 ................../ 96 146160 .................... 1 1 ■ । ' ' 1 1

mlz-> oV 20 70 1 -HH 40 49 60 Fn'Ir 118 H 11‘00‘1‘11191101‘10-0—n—‘[ITT1‘1111 80 100 120 140 160 180 200 220 240 260 280 300 320 22.20 22.40 22.60 22.80 23.00 m/z 191.10 N 18.25%| Abundance #80953: 2-Propenal, 3-(3,4-dimethoxyphenyl)- 192 (1 161

5000 ’I1’ITT’’ I , 22.20 22.40 22.60 22.80 23.00 52 77 91 121 177 m/z 193.10 18.02%|

miz-> oV 20 —ll 106 40 ill li || li 60 138 ’1 11'111 r11111111 L - 80 100 120 140 160 180 200 220 240 260 280 300 320 Abundance #81033: Phenanthrene, 9-methyl- 192 — * 1 1 ' 1 TT 22.20 22.40 22.60 22.80 23.00 5000 m/z 146.10 16.47%|

96 165 i 0 —393.814115139 4 ■ i ■ ■ • ■ i ■ ■ ■ ■ i ■4' ‘ i1 1 ■' i 1 ■ ■ 11' ■ ■ ■ i' ■1 ■ i /z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 Abundance #81065: Isoquinoline, 1,2,3,4-tetrahydro-1-[2-nitrobenzyl]... ,................................................ 192 22.20 22.40 22.60 22.80 23.00 m/z 96.00 16.27%| 5000

176 49 63 78 92 ,. 117131 148162 . . , 0 TCOT—mmTdm 11'1 '11 1rrTt 1111 ।11111 ■ 207222236250264280295311 328 i1'' " i ■ " 11'1111IT'111'1111111111 " 11 I I r I miz—> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 22.20 22.40 22.60 22.80 23.00

10895.D 050102.M Fri May 17 15:03:56 2002 Page 5

NYC-WTC_000024079

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NYC-WTC_000024079Source: NYC Law Department, mirrored locally

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