GCMS analysis results, sample AE09331, May 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\050902\9331.D Vial: 21 Acq On : 10 May 2002 8:24 am Operator: Mclean Sample : 5/8 eh Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 6 2-Propenal, 3-(3,4-dimethox... Concentration Rank 6

R.T. EstConc Area Relative to ISTD R.T. 22.58 0.36 ug/L 622331 Phenanthranene-dl0 22.96 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Propenal, 3-(3,4-dimethoxyphen... 192 C11H1203 004497-40-9 45 2 (-)-1,2,3,4-Tetrahydroisoquinoli... 251 C13H17NO4 1000127-91-1 4 3 Phenanthrene, 1-methyl- 192 C15H12 000832-69-9 42 4 Phenanthrene, 2-methyl- 192 C15H12 002531-84-2/40 Abundance Scan 3318 (22,575 min): 9331 ,D (-3309) (-) m/z 192.10 100.00% 192

5000

82 96 | 160 1.20132 146 160 .... n... / 22.20 22.40 22.60 22.80 23.00

m/z-> 42 66 0—PPTTT i 1 । । i • i • i-1 20 40 60 80 100 4 —— — 120 140 160 180 200 220 240 ■ i 1 ' 1 1 i ■ ' 1 ' i ■ ■ ' ■ i m/z 191.10 19.95%

Abundance #80953:2-Propenal, 3-(3,4-dimetboxyphenyl)- 192 161

5000 22.20 22.40 22.60 22.80 23.00 77 91 103 121 149 177 m/z 146.10 14.83% 52 64 138

m/z-> oV 20 -H 40 — 60 80 li — ■ i 1 ■ ■ ' i' ■ ■ ' i ■ 100 120 TII — 140 160 180 ■ i 1 ' ■ ■ i ■ ■ ‘ 1 i ■ ■ ' ‘ i 200 220 240 Abundance #81004: (-)-1,2,3,4-Tetrahydroisoquinolin-6-ol-1 -carboxyli... 102 ......... 4...... 22.20 22.40 22.60 22.80 23.00 5000 m/z 96.00 13.43% 177 42 53 65 77 96 107118 132 148 161 206 222 236 251 0H I ! । I r rr i4m11e 1**r 1 "l I rh i 1 i i "I" I I rh-n i 14" 11 '■ i ■ ■ ■ ■ i ■ • ■ 1 i ' ■ ■ ■ i n/z-> 20 40 60 80 100 120 140 160 180 200 220 240 Abundance #125856: Phenanthrene, 1-methyl- _________ A______ J_ 111’1 1’’‘ * I ■ ' * ■ I ‘ 1 TIT 102 22.20 22.40 22.60 22.80 23.00 m/z 193.10 12.76%

5000

96 P . 27 39 51 63 82 1 115126 139 152 12 178 01 11111’ 1"I r"' 1 '"I i''' •' i ' 'i'' i'1 TT m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 22.20 22.40 22.60 22.80 23.00

9331.D 050102.M Mon May 13 11:42:38 2002 Page 9

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