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GC/MS results for unknown compounds and surrogates, sample AE10985, May

Machine-extracted title · confidence 100%

Laboratory report showing GC/MS analysis of sample AE10985 with surrogate recovery data for 2,4-DDD.

NYC-WTC_000024014–000024037

Folder label: “GCMS X 5/10/02 A 5/14/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\051402\10985.D Vial: 14 Acq On : 15 May 2002 12:06 am Operator: Mclean Sample : 5/10 kb Inst Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 10 Benzonitrile, 3-methyl- Concentration Rank 6 R.T. EstConc Area Relative to ISTD R.T.

30.98 0.33 ug/L 294528 Chrysene-dl2 30.81

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Benzonitrile, 3-methyl- 117 C8H7N 000620-22-4 9/ 2 1,2,3,4,5,6,7,8-Octahydrotriphen... 236 C18H20 013090-93-2 /9 3 2-Propen-1-one, 1-(4-methylpheny... 237 C16H15NO 052939-91-0 9 4 Benzyl nitrile 117 C8H7N 000140-29/4 9 Abundance Scan 4748 (30.977 min): 10985.D (-4747) (-) m/z 236.10 100.00% 1 7 236

5000 78 107 208

44 30.60 30.80 31.00 31.20 31.40 0- 1 1 I ।'' 1 ' 1 1 1 1 ' I ' ' ' 1 1 * ‘ 1 1 m/Z 117.40 89.88% miz-> 40 60 80 100 120 140 160 180 200 220 240 Abundance #120507: Benzonitrile, 3-methyl- 117

5000 90 — allMap "Pro l r । l ■ ■ 30.60 30.80 31.00 31.20 31.40 m/ z 23 9.20 73.65% 39 51 63 75 0111s all i" ill ' ") '"I1 । r ' ' ' । ■ ' ' ■ । 1 ■ 1 1 । 1 1 1 1 । 1 1 1 1 । 1 1 ■ ■ । ■ ■ miz-> 40 60 80 100 120 140 160 ’ 180 200 220 240 Abundance #90685:1,2,3,4,5,6,7,8-Octahydrotriphenylene 236 .............. ..........................

30.60 30.80 31.00 31.20 31.40 5000 m/z 115.90 60.00% 165 178 193 208 89 | 115 152 0— —, , I , i ' l‘" i ' _ i hll II m/z-> 40 60 80 100 120 140 160 180 200 220 240 Abundance #90697: 2-Propen-1 -one, 1-(4-methylphenyl)-3-phenyl-, oxim... । i ■ ■ ■ । । ■ 113 । । । . Z16 30.60 30.80 31.00 31.20 31.40 220 m/z 120.10 58.35%

5000 77 91 51 105

0 m/z-> 40 60 80 100 120 140 160 180 200 220 240 30.60 30.80 31.00 31.20 31.40

10985.D 050102 .M Thu May 16 14:42:40 2002 Page 13

NYC-WTC_000024031

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NYC-WTC_000024031Source: NYC Law Department, mirrored locally

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