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GC/MS results for unknown compounds and surrogates, sample AE10984, May

Machine-extracted title · confidence 100%

Laboratory report showing GC/MS analysis of sample AE10984 with surrogate recovery data for 2,4-DDD.

NYC-WTC_000023991–000024013

Folder label: “GCMS X 5/10/02 A 5/14/02

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Scanned page image, NYC-WTC_000024004
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NYC 9/11 Public Portal Document

Data File : C:\MSDCHEM\l\DATA\051402\10984.D Vial: 13 Acq On : 14 May 2002 11:17 pm Operator: Mclean Sample : 5/10 kb Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 5 Benzene, 1,2,3,5-tetrachlor... Concentration Rank 12

R.T. EstConc Area Relative to ISTD R.T. 21.39 0.21 ug/L 315351 Phenanthranene-dl0 22.96 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Benzene, 1,2,3,5-tetrachloro-4,6... 242 C8H6C14 000877-09/8' 95 2 Benzoic acid, 2,4,6-trichloro- 224 C7H3C1302 000050-43-147 3 2-Chloroaniline-5-sulfonic acid 207 C6H6C1NO3SI 000098-36-2 46 4 Quinoline, 3-bromo- 207 C9H6BrN 005332-24-1 43 Abundance Scan 3117 (21.393 min): 10984.D (-3106) (-) m/z 206.90 100.00% 207 244

5000 136 ----- —51 — 85 102 172 229

n/z- > ol :20 40 60 ?11L 80 100 120 140 160 180 200 Il i 220 240 21.00 21.20 21.40 21.60 21.80 m/z 2 09.00 83.61% Abundance #84890: Benzene, 1,2,3,5-tetrachloro-4,6-dimethyl- 207 244 -- 5000 136 21.00 21.20 21.40 21.60 21.80 m/z 243.90 69.84%

miz-> 0 20 As 40 51. 74 85 99 60 80 171 II— 157, l | , 193, ? 100 120 140 160 180 200 229 l( IT 220 240 Abundance #84889: Benzoic acid, 2,4,6-trichloro- 207 ...................... Il........................ 224 21.00 21.20 21.40 21.60 21.80 5000 m/z 241.90 51.89% 74 109 144 179 2 3,7 50 61 97 121 133 196 /z-> 0 Iif / lidl/, spiler - 22 L 60 4— -- 11,1111 Th———— 20 40 60 80 100 120 140 160 180 200 220 240 Abundance #84878:2-Chloroaniline-5-sulfonic acid ■ i ■ ■ ‘ ■ i r ■ ' ■ i 2017 21.00 21.20 21.40 21.60 21.80 m/z 136.00 37.31%

5000 43 EE 90 ...... II.l|rl +nyhdvppran, 0-II" 69 | , , 114126 145 111 11" , 1" 0 1 1 m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 21.00 21.20 21.40 21.60 21.80

10984.D 050102.M Thu May 16 14:41:38 2002 Page 9

NYC-WTC_000024004

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NYC-WTC_000024004Source: NYC Law Department, mirrored locally

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