GC/MS results for unknown compounds and surrogates, sample AE10984, May

NYC 9/11 Public Portal Document Ip— tit* -M

Data File : C:\MSDCHEM\l\DATA\051402\10984.D Vial: 13 Acq On : 14 May 2002 11:17 pm Operator: Mclean Sample : 5/10 kb Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 4 3-Pyrrolidinol Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

7.72 0.43 ug/L 448707 1,4 -Dichlorob'enzene-d4 9.94

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-Pyrrolidinol 87 C4H9NO 040499-83-0 37 2 2-Hexanone, 5-methyl- 114 C7H140 000110-12-3 28 3 2 -Hexanone, 5-methyl- 114 C7H140 000110-12-3 28 4 Methyl 1-methylcyclopropyl ketone 98 C6H10O 001567-75-5 14 Abundance Scan 790 (7.721 min): 10984.D (-785) (-) m/z 43.10 dOO.00% 40

5000 58 87 98 7.40 7.60 7.80 8.00 51.1|| I, 69..... ■' । i'1 । । 0- 1 1 i ■ mo । । । । । । i > । 11 +r 1 i 1 ■ 1 1 i 1 1 1 1 i ■ ' ■ 1 i ' ■ I । • ■ ■ ■ i ■ ■ • ■ । । m/ z 58.10 23.91%

U m/z-> 10 20 30 40 50 60 70 80l 90 100 110 120 Abundance #4163: 3-Pyrrolidinol 43

Mny/W 5000 ■ 1 ' i ■ ■ ■ ■ i ■ ■ ' ‘ i ' 1 ' ' i ■ ■ ■ ■ i 7.40 7.60 7.80 8.00 57 87 m/ z 87.10 20.52% 68

m/z—> 0- ■ • i ■ ■ • ■ i ■ • • • । 10 20 30 ■ i • 40 —51l 50 60 70 771—00011.... + 80 90 100 110 120 Abundance #5735:2-Hexanone, 5-methyl- 43 A 7.40 7.60 7.80 8.00 5000 m/z 57.10 11.06% 58 15 27 71 0- ' 1 1 * 41374 +5141+544 81 99 114 m&-> 10 20 30 40 50 60 70 80 90 100 110 120 Abundance #109705:2-Hexanone, 5-methyl- TI 43 7.40 7.60 7.80 8.00 m/z 41.10 10.98%

5000 58

/z-> 0 ......... 10 20 b ... 30 . 40 27 71 70 85 99 114 -11 IIl|1 ' ' TII—————m———m————mBTTETT 50 60 80 90 100 110 120 Nmhmm/Mwnto““) 7.40 7.60 7.80 8.00

10984.D 050102.M Thu May 16 14:41:38 2002 Page 8

NYC-WTC_000024003