GC/MS results for unknown compounds and surrogates, sample AE10984, May

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Data File : C:\MSDCHEM\1\DATA\051402\10984.D Vial: 13 Acq On : 14 May 2002 11:17 pm Operator: Mclean Sample : 5/10 kb Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\l\METHCDS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 3 2-Pentanone, 4-hydroxy-4-me.. Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

5.98 19.60 ug/L 20532300 1,4 -Dichlorobenzene-d4 9.94 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 2-Pentanone, 4 - hydroxy - 4 - me t hyl - 116 C6H12O2 000123-42-2 86 2 2 -Pentanone, 4 -hydroxy-4 -methyl- 116 C6H12O2 000123-42-2 2 3 2 -Pentanone, 4-hydroxy-4-methyl - 116 C6H1202 000123-42-2 4 Acetone______ 58 C3H60 000067-64- 32 Abundance Scan 494 (5.982 min): 10984.D (-485) (-) m/z 43.10 100.00% 43

5000 59 101 5.60 5.80 6.00 6.20 6.40 ............... O+ TIIu ■i-r-p 11111 4 37,1 53, ItTt 1" 1 11‛l 69 77 83 i ‘ [ ■ 1 i 1 1 ' ' i ■ ■ 1 ' i , | 117 125 ' i 1 ■ ' 1 i ■ ‘ 1 ' i ' ■ ■ ' i ' ' m/z 59.10 35.32% miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #109755:2-Pentanone, 4-hydroxy-4-methyl- 43

5000 59 5.60 5.80 6.00 6.20 6.40 m/z 58.10 21.97% 15 101 01 25,31 37, , X T— ’ ’ I ' 53, 1 " I “'l I 1 ■ ■ ' i 1 ■ ■ ■ i 83 ' i ' ' 1 .1 i | 1 ■ ■ ■ i 1 ■ ' ■ i 1 ■ ' ■ i ' ' n/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #109756: 2-Pentanone, 4-hydroxy-4-methyl- 43 .. ............ .................................... .. . 5.60 5.80 6.00 6.20 6.40 5000 59 m/z 101.10 13.48%

83 — 93 93 101 । O+ . ..... . "■i "'i I ■ ■ ' ■ i ■ ■ ■ ‘ i ' ' ‘ ■ i 1 ' ' 1 i 1 1 ' ■ i 1 ■ ' ' i ' ' ‘ 1 i ' ‘ m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #5851:2-Pentanone, 4-hydroxy-4-methyl- 43 ■ i ■ ■ ■ । i ■ 5.60 5.80 P) 6.006.20 6.40 m/ z 41.15 5.95%

5000 59 101 0 PrpP—P) 27 37 53, Ml/l +TT4+ 67 77 83 91 , | I ■ 1 1 ■ i 1 1 1 ' i 1 1 ‘ ■ i ‘ ■ 1 1 i 1 r ■ 1 i ■ ' 1 ■ i 1 ‘ ' ■ i ' 1 TTTu IP 17 1T ''T1'1 IFT" /z—> 10 20 30 40 50 60 70 80 90 100 110 120 130 5.60 5.80 6.00 6.20 6.40

10984.D 050102.M Thu May 16 14:41:38 2002 Page 7

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