GC/MS results for unknown compounds and surrogates, sample AE10984, May

NYC 9/11 Public Portal Document

Data File : C:\MSDCHEM\l\DATA\051402\10984.D Vial: 13 Acq On : 14 May 2002 11:17 pm Operator: Mclean Sample : 5/10 kb Inst Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\l\METHCDS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 2 Butane, 2,2,3,3-tetranitro- Concentration Rank 8

R.T. EstConc Area Relative to ISTD R.T.

3.76 0.34 ug/L 352158 1,4-Dichlorobenzene-d4 9.94

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Butane, 2,2,3,3-tetranitro- 238 C4H6N4O8 020919-97-5 4 2 Acetic acid, dichloro-, ethyl ester 156 C4H6C12O2 000535-15-9/4 3 Butane, 2,3-dimethyl- 86 C6H14 000079-29-8 3 4 Butane, 2,3-dimethyl- 86 C6H14 000079-29-8 2 Abundance Scan 115 (3.755 min): 10984.D (-108) (-) m/z 43.10/ 100.00% 4)3

5000 WvwA/nuw , 51 01 1 . ....... 1354+ + 63 85 1101111’1111111111U1111’111"1111’T"-T’1"*111E’1’111117 340 m/z 3.60 3.80 51.10 4.00 4.20 13.14% rn/z-> Abundance 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 #3995: Butane, 2,2,3,3-tetranitro- Yhus,M"h"yhp-mabop 30 43

5000 340 3.60 3.80 4.00 4.20 53 m/z 85.00 8.48% 15

miz-> Of 11 lh-. p-,4 1H 10 20 30 + +44——60 6970 80 THT 40 50 86rrp-i-n-p- i1 ‘• i1''11 90 100 110 120 130 140 150 160 11''11 r ■ ■ ■ i ■1

Abundance #108006: Acetic acid, dichloro-, ethyl ester 29 AAA i t qan « As , nA 340 3.60 3.80 4.00 4.20 5000 m/ z 83.00 8.45%

— , 37, 48 83 I. 57 65 73, || 93 101 111 123 140 154 ol 1E2—1—-mamm11’1111110011110’1!11—*01001—UtT m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 Abundance #109394: Butane, 2,3-dimethyl- 43 '*0 mi ' A-4-4—4 340 3,60 3.80 4.00 4.20 m/z 38.10 6.15% 5000

71 27

/z-> 0 rI"" 10 20 l 11 H4 30 40 Tii 50 55 62 ।60 70 86 '' i " 1' i'1" i'''' ir ■'11''1' r " ' i ■ ■ 80 90 100 110 120 130 140 150 160 nQMuM—MLAAAAOI 3.40 3.60 3.80 4.00 4.20

10984.D 050102.M Thu May 16 14:41:36 2002 Page 6

NYC-WTC_000024001