GC/MS results for unknown compounds and surrogates, sample AE10984, May

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Data File : C:\MSDCHEM\l\DATA\051402\10984.D Vial: 13 Acq On : 14 May 2002 11:17 pm Operator: Mclean Sample : 5/10 kb Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\l\METHCDS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 1 Acetonitrile, dichloro- Concentration Rank 7

R.T. EstConc Area Relative to ISTD R.T.

3.63 0.34 ug/L 352697 1,4-Dichlorob'enzene-d4 9.94

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Acetonitrile, dichloro- 109 C2HC12N 003018-12- 0 2 Acetonitrile, dichloro- 109 C2HC12N 003018-12- 3 3,3-Dichloropropyne 108 C3H2C12 1000222-23-9 25 4 Allyl mercaptan 74 C3H6S 000870-23-5 25 Abundance Scan 94 (3.631 min): 10984.D (-89) (-) m/z 74.00 100.00% 74 82 5000

38 47 . .... M> 3.20 3.40 3.60 3.80 4.00

n/z-> Of - 10 20 30 40 50 F8ppL 60 70 80 । 108 I 1 । 1 1 ' । । 1 1 'i । 1 90 TIB 100 110 m/z 82.00 60.94% Abundance #28338: Acetonitrile, dichloro- 74

5000 82 A 3.40 3.60 3.20 3.80 4.00 47 m/z 76.10 32.99% 35

miz-> Of 12 1 1 । ' 'I । । । 10 20। 2 — 30 40 ......................... ' 50 60 70 80 . 90 108 100 110 Tid I ' | । 1 । 1 | | 1 1 r। . i > i ।

Abundance #115342: Acetonitrile, dichloro- 74 ----- 35 3.20 3.40 3.60 3.80 4.00 5000 82 m/z 84.00 28.45%

01 ————— I 1 1 1 ''i 1 1 1 ■ i - । ■ 47

1 ' I ' ' ■ ■ i 1 ' ' ■ I 1 1 1 1 I M/wyakaya m/z-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #28312:3,3-Dichloropropyne 74 3.20 3.40 3.60 3.80 4.00 m/ z 47.05 25.39%

5000 38 47 vW/"moap /z-> 0- ■ ■ । ■ ■ ■ • । । 10 20 . 26,. .mu,... 30 40 | । 53 60 1 I' 1 1 1 1 111'I1 50 60 70 । 82 108 ' i 1 1 ■ 1 i ■ ' ■ ■ i 1 ' 1 1 1 1 1 1 1 I 80 90 100 110 3.20 3.40 3.60 3.80 4.00

10984.D 050102.M Thu May 16 14:41:34 2002 Page 5

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