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GC/MS results for unknown compounds and surrogates, sample AE10980, May

Machine-extracted title · confidence 100%

Laboratory report showing GC/MS analysis of sample AE10980 with surrogate recovery data for 2,4-DDD.

NYC-WTC_000023887–000023903

Folder label: “GCMS X 5/10/02 A 5/14/02

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Scanned page image, NYC-WTC_000023899
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NYC 9/11 Public Portal Document Library search Compound Report

Data File : C:\MSDCHEM\1\DATA\051402\10980.D Vial: 9 Acq On ' : 14 May 2002 8:01 pm Operator: Mclean Sample : 5/10 kb Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\l\METHQDS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 5 Phenanthrene, 9-methyl- Concentration Rank 7 R.T. EstConc Area Relative to ISTD R.T. 22.58 0.30 ug/L 330688 Phenanthranene-dl0 22.95 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 53. 2 Bitoscanate 192 C8H4N2S2 004044-65-9 52 3 1,5-Naphthalenedithiole 192 C10H8S2 1000223-69-5 45 4 Phenanthrene, 2-methyl- 192 C15H12 002531-84-2 42 Abundance Scan 3319 (22.580 min): 10980. D (-3309) (-) m/z 192.10 100.00% 192

5000

82 96 146 1 160 22.20 22.40 22.60 22.80 23.00 42 66 I I 0 mm t • •■■ | /1 ■ | ■ I > |I I I > | > I I 1 | tt 111 ■"120 111'1 "111" I " " I m/z 191.10 18.94% 11" " I" " i ‘I nfe-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #81033: Phenanthrene, 9-methyl- 192

5000 22.20 22.40 22.60 22.80 23.00 m/z 146.10 16.67% 29 39 51 63 74 83 T 115 126 139 152 165 176 | | 0 TIOOTTCTTTTTTTTTTTTmt 1’1 nfe-> 20 30 40 50 60 70 80 90 100 110 120 130.140 150 160 170 180 190 200 Abundance #125828: Bitoscanate 192 2...... 22.20 22.40 22.60 22.80 23.00 5000 m/z 193.00 15.29%

. 50 63 75 90 134 160 A 1 102

n/z-> 0 ---494++4 —H, 122 148 1 rtrrrtho । ItH I'" i"'-ii'" '' 176 । ■ ■ 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200- । ।ij। ।

Abundance #80950:1,5-Naphthalenedithiole i ■ । । ■r r mr 1 I 1 1 1 1 I ' ' 192 22.20 22.40 22.60 22.80 23.00 m/z 96.00 14.10% 5000 115 128 159 40 57 69 79 96 106 147 177 0 --------------------- ‘C । "i pur ‘ 1‘4 miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.20 22.40 22.60 22.80 23.00

10980.D 050102.M Thu May 16 14:36:26 2002 Page 8

NYC-WTC_000023899

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NYC-WTC_000023899Source: NYC Law Department, mirrored locally

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