GCMS instrument log for sample AE09673, May 2002

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Data File : C:\HPCHEM\1\DATA\MAY2002\9673.D Vial: 11 Acq On : 20 May 2002 5:01 pm Operator: Sample : EXTRACTED 5/9 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0520.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L Peak Number 2 S-(-)-2-Methylbutylamine Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 9.92 0.71 ug/1 37988 1,4-Dichlorobenzene-d4 12.14 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 S- (-) -2-M<ethylbutyl amine 87 C5H13N 020626-52-2 7 2 4-Penten—2-one, 4-methyl- 98 C6H10O 003744-02-3 7 3 3 -Pyrro dinol 87 C4H9NO 040499-83-0 5 4 4-Pente -2-one, 3-methyl- 98 C6H10O 000758-87-2 5 Abundance Scan 532 (9.918 min): 9673.D (-) m/ z 43.05 100.00% 43

5000

58 Tad /1111III

0100—0 39, +1 83 Y 98 m/ z 58.10 " i ■' " i " " i1 ‘1' i ‘1‘ i " " i " 1' i " ■' i " 9.60 9.80 10.00 10.20 17.30% miz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #764: S-(-)-2-Methylbutylamine 33

5000 9.60 9.80 10.00 10.20 m/ z 87.05 14.64% mpr . . ,41 ... 56 ... 70.... 87...... ' “ * i1"11" " i11" i" " i11 n i “'11" " i11" i" " i"" i'1 ,i r "11'11111"' i11 mfz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #1244:4-Penten-2-one, 4-methyl- 43 9.60 9.80 10.00 10.20 5000 m/z 59.10 10.90% 83 29 39 55 98 ■ ■ । ■ > ■ ■ । ■ I > I I " < । I i. ■ । I I I 1 +-mmmmmTTTT qp m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #752:3-Pyrrolidinol 43 9.60 9.80 10.00 10.20 m/ z 41.05 10.45% 5000

57 87 68

m/z—> m -+ I I | I . . > | I J I | > I ! I j I .. I | I

20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 II J I|IIII|II II|I!II |II luml 9.60 9.80 10.00 10.20

9673.D GCMS0520.M Tue May 21 11:38:30 2002 Page 2

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