GC/MS analysis results, sample AE10062, May 23 2002

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Library Search Compound Report Data File : C:\HPCHEM\l\DATA\MAY2002\10062.D Vial: 13 Acq On : 20 May 2002 6:58 pm Operator: Sample : EXTRACTED 5/9 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0520.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L Peak Number 2 S-(-)-2-Methylbutylamine Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T. 9.92 0.63 ug/1 35795 1,4-Dichlorobenzene-d4 12.14 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 S- (-) -2-Meth; lbutylamine 87 C5H13N 020626-52-2 9 2 Propane, 1- -methylethoxy) - 102 C6H140 000627-08-7 9 3 Acetic acid , 1-methylethyl ester 102 C5H10O2 000108-21-4 9 4 Acetic acid , 1-methylpropyl ester 116 C6H1202 000105-46-4 9 Abundance > Scan 533 (9,921 min): 10062.D (-) m/z 43.05 100.00% 43

5000

58 87 9.60 9.80 10.00 10.20 .... 11111/111336.1) +514— 98 ■ i ■'' ■ ।" i ■" ■ ।"111 ■ TTTTTPT m/ z 58.10 18.13% mfe-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 Abundance #764: S-(-)-2-Methylbutylamine 33

5000 1*‘1I 9.60 9,80 10.00 10.20 m/z 87.05 16.70% .. ,, ,.. 41 ... 56.... 70.... 87 * i'1 ■' j'1'111''11' ‘1111'11J' * • * i ’ ‘1111 ■1 ‘ j * ‘ ‘ ■ i ■ ■1 * i * • •' i ‘ * i * * ‘ ■ i ■11' i *1111 ■ ■ ■ ■ i *1 * * i ‘11111 m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 Abundance #63556: Propane, 1-(1-methylethoxy)- 43 9.60 9.80 10.00 10.20 5000 m/ z 59.10 13.51%

27 71 87 87 । 59 73 102 " i'1" i ■'" J ■ ■ ■ i'" U' 1 1'" । ■11"'' i ’"' ।।। ।" i11" i1'1111111111" r1111111" i1 m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 Abundance #1719: Acetic acid, 1-methylethyl ester 43 9.60 9.80 10.00 10.20 m/ z 41.15 13.19% 5000

61 27 0/ 87 1/001700/ a.

n/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 9.60 9.80 10.00 10.20

10062.D GCMS0520.M Tue May 21 11:37:31 2002 Page 2

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