GCMS instrument log for sample AE10064, May 2002

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Library Search Compound Report Data File : C:\HPCHEM\l\DATA\MAY2002\10064.D Vial: 15 Acq On : 20 May 2002 8:56 pm Operator: Sample : EXTRACTED 5/9 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0520.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L Peak Number 2 Acetic acid, 1-methylpropyl es Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 9.92 0.78 ug/1 45754 1,4-Dichlorobenzene-d4 12.14 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Acetic acid, 1-methylpropyl ester 116 C6H1202 000105-46-4 25 2 4-Penten-2-one, 4-methyl- 98 C6H10O 003744-02-3 7 3 5-Hexen-2-one 98 C6H10O 000109-49-9 7 4 S- (-)/2-Methylbutylamine _________ 87 C5H13N 020626-52-2 7 Abundance Scan 532 (9.918 min): 10064.D (-) m/z 43.05 100.00% 43

5000

58 87 98 | 9.60 9.80 10.00 10.20

m/z—> m38L i"" i1" ‘ i" “ i + HlmFA. i 49 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105 Irh . | ! U I | . J I | ! I I . | ! U ! | m/ z 58.10 18.66% Abundance #64338: Acetic acid, 1-methylpropyl ester 43

5000 1 ‘ । 1 1 9.60 9.80 10.00 10.20 56 87 m/ z 87.05 15.23% 15 27 73 101 I 61 -TT t omnpnujhhnihu TTTTTTTTHTTTTTTTTTTTTTTTTTTTTTTTTTTTTT m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105 Abundance #1244:4-Penten-2-one, 4-methyl- 43 9.60 9.80 10.00 10.20 5000 m/z 41.05 11.29% 83 29 ort 55 98 mppg rH 11'11' 111" 111111'111111 ' 111" I"11111111111' 111111 m/z—> +mrpmHnj 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105 Abundance #63205:5-Hexen-2-one 43 9.60 AALAAAACN 9.80 10.00 10.20 m/ z 59.10 10.99% 5000

27 55 15 - | | 38 , 50 83 98 "'‘i'‘' I'''' i''''i'1'11''' i''11111 11‘'■i■ ■1 ■ 1'11111''i111'11'111'1'11'111111111111' 111111111'|11111 m/z—> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105 9.60 9.80 10.00 10.20

10064.D GCMS0520.M Tue May 21 11:37:56 2002 Page 2

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