GCMS instrument log for sample AE10065, May 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\HPCHEM\1\DATA\MAY2 002\10065.D Vial: 16 Acq On : 20 May 2002 9:55 pm Operator: Sample : EXTRACTED 5/9 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0520.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 Acetic acid, 1-methylpropyl es Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 9.92 0.73 ug/1 40608 1,4-Dichlorobenzene-d4 12.15 Hit# of Tentative ID MW MolForm CAS# Qual 1 Acetic/acid, 1-methylpropyl ester 116 C6H1202 000105-46-4 25 2 Acetone 58 C3H60 000067-64-1 9 3 5-Hexen-2-one 98 C6H10O 000109-49-9 7 4 2-Propanone, 1-eye1opropy1- 98 C6H10O 004160-75-2 5 Abundance 1 Scan 532 (9.919 min): 10065.D (-) m/z 43.05 100.00% 43

5000

58 87 9.60 9.80 10.00 10.20 36 , | | 69 | 98 1111’1111111111011311311111011153 +TTTTHTHTTTTTTTTTTTTTTTTTTTTTTTTTHTTTTTTTTTT m/ z 58.10 17.58%| m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105 Abundance #64338: Acetic acid, 1-methylpropyl ester 43

5000 A 9.60 9.80 10.00 10.20 56 87 m/z 87.05 14.95%| 15 27 61> • • i • ■ > ■ । ■I73■।■■■■।• i ■ Il • ■ । ■>■■। TTT mmH +tTTTTTT ■ ■•[. 11I ■■ 11 101 m/z—> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105 Abundance #62322: Acetone 43 ' ' 1 1 ' ‘ 1 i ■ ■ ■ ■ । i । 1 * । । ■ ■ ■ । 9.60 9.80 10.00 10.20 5000 m/ z 59.10 11.25%| 58 27 msyosgasgllg 11 > ■ ■ ■ j ■ ■ >. i ■ ■ 11111111111111111111111111 [ 1111111111111111111111111

m/z—> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105 Abundance #63205: 5-Hexen-2-one 1 1 i 1 ' ' ■ i ■ ■ 1 1 i ■ 1 1 1 i 1 1 1 ' i 43 9.60 9.80 10.00 10.20 m/ z 41.10 10.61%|

5000

27 55

m/z—> 15 I - | 38 , 50 83 98 " " r "' r "' i" '' r1" i" ‘1 r " ■ i11111 ■'" i"1' 11" ■ i"11111111" " 111" I"111" " I"111"1111"' I"111 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105 ACM 9.60 9.80 10.00 10.20

10065.D GCMS0520.M Tue May 21 11:38:08 2002 Page 2

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