GCMS calibration table and instrument parameters, Apr 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\HPCHEM\l\DATA\APR1202\8481.D Vial: 26 Acq On : 16 Apr 2002 9:08 am Operator: Sample : gc/ms scan 4/10 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 2 3-Penten-2-one, 4-methyl- Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T.

7.15 2.91 ug/1 416617 1,4-Dichlorobenzene-d4 12.23 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-Penten-2-one, 4-methyl- 98 C6H10O 000141-79-7 (94J 2 4-Hydroxy-4-methylpentanone 116 C6H1202 000000-00-0 74 3 Cyclohexane, methyl- 98 C7H14 000108-87-2 72 4 2-Pentene, 3,4-dimethyl-, (E)- 98 C7H14 004914-92-5 64 Abundance Scan 230 (7.155 min): 8481 D (-) m/z 82.95 100.00% 55 83

5000 98 43 1/m 680 7.00 7.20 7.40 " 111'' 11'1' I -H 47 51 | Irr 62 67 3& , —mp 11" " i ‘1 I 'l 11! 11111 'i “ " I'1' ‘ 111111'1111" 77 m/z 55.00 77.99% mlz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #63216: 3-Penten-2-one, 4-methyl- 55 83 43 98

5000 39 ------------------------------ 680 7.00 7.20 7.40 m/z 98.05 44.68% - 511 —mmmmm ' i1 " ‘ r 1111 " 111' " r 1 ■ > । " " ।11111" " ।111 mz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #3236:4-Hydroxy-4-methylpentanone 83 55 I I I 1^1 I I I I I [ I I I I I 1 I ng 98 680 7.00 7.20 7.40 5000 m/z 42.95 37.25% 43

37 51 । 79 T, YO I " '11 I' ■ ■11 11111111111 —TIPTTTTTTTTTT TITrr — T’T’’I 111111 r 1 m/z—> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #1326: Cyclohexane, methyl- I T — R T I / ! M= r 4 83 680 7.00 7.20 7.40 55 m/z 39.05 25.75%

5000 98 42 27 69 I ! | I I । I I I I | I I I I | I । I'1'11 ’ 1’111 " i1" ' r 1 TTp I I ■ I I I I I I I I I > 1 1 r111111 । । । । T r । । r ri 1III* "I । 1i | f n/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 6.80 7.00 7.20 7.40

8481.D GCMS0412.M Wed Apr 17 09:49:07 2002 Page 2

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