GCMS calibration table for TCLP analysis, May 2002

NYC 9/11 Public Portal Document

Data File C: \HPCHEM\ 1 \DATA\MAYO 302\9578.D vial: 51 Acq On 5 May 2002 5:01 pm Operator: Sample GC/MS SCAN 4/23 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L Peak Number 1 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T. 8.16 22.71 ug/1 1568610 1,4-Dichlorobenzene-d4 12.19 Hit# of Tentative ID MW MolForm CAS# Qual

1 2-Pentanone, 4 - hydroxy-4-methyl - 116 C6H1202 000123-42-2 64 2 CH2=CHCH2C(0)OCH3 100 C5H802 003724-55-8 9 3 Acetone 58 C3H60 000067-64-1 7 4 2-Propyn-1-ol , acetate 98 C5H602 000627-09-8 5 Abundance / Scan 340 (8.160 min): 9578.D (-) m/ z 43.05 100.00%| 43

5000 59

101 1 1 i 1 11 11 1 1 7.80 8.00 8.20 8.40 8.60

m/z-> .................................. 38 1 10 20 30 40 +53+ 50 69 77 83 ————— 60 70 80 90 , | 100 110 m/z 59.10 42.25% Abundance #64274:2-Pentanone, 4-hydroxy-4-methyl- 43

5000 59 7 80 8.00 8.20 8.40 8.60 m/z 58.10 16.71% 27 101

mlz-> 10 20 30 40 +49 50 | PPP 60 70 80 83 90 1 1, 1 100 110 Abundance #1448: CH2=CHCH2C(O)OCH3 43 7.80 8.00 8.20 8.40 8.60 5000 m/z 101.15 13.3 9%|

_8 58 72 I*****/*** 1 00 ' i ■ ■ ■ ■ i ■ < > ■ i • ■ ■ < l i 10 20 30 40 50 60 70 80 90 100 110 Abundance #94: Acetone _ . ........... 43 7.80 8.00 8 20 8.40 8.60 m/z 41.05 7.09% 5000 15 58 27 ■ ■ ■ i ll 1 i ■ 11,1 ■ 1 ■ ‘ 1 i 1 ■ I ' ' ' ' i ' ' ' ' i ' ' ' ■ i ■ ' ' ' i ' ' ' ■ i 1 m/z—> 10 20 30 40 50 60 70 80 90 100 110 7.80 8.00 8.20 8.40 8.60

9578 .D GCMS0501.M Tue May 07 15:02:00 2002 Page 1

NYC-WTC_000023332