GCMS scan report for Method 508, April 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\020419\08485.D Vial: 22 Acq On : 20 Apr 2002 4:48 am Operator: Nefliu Sample : sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\SCAN020418.M (Chemstation Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1 ********************************************************************* Peak Number 8 1-Pyrenecarboxaldehyde hydr... Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

39.22 0.46 ug/1 824590 Chrysene-dl2 39.93

Hit# /Of 5 Tentative ID MW MolForm CAS# Qual

1 1-Pyrenecarboxaldehyde hydrazone 244 C17H12N2 076465-53-7 64 /O 2 p-Terphenyl-d14 244 C18D14 001718-51-0 59 3/1,3-Benzoxazine, 3-methyl-2-phen... 244 C15H20N2O 1000138-91-6 42 A 1,4-Cyclohexadiene, 6-methylene-... 244 C19H16 018636-59-4 42 undance Scan 6152 (39.226 min): 08485.D (-6096) (-) m/z 244.10 100.00% 2-4

5000 40 . ................................ A................. 122 51 84 99 197 38,80 39.00 39.20 39.40 39,60 01 ..... 'H' il i Il I rn/z 243.10 55.61% miz-> 20 40 60 80 100 120 140 160 180 200 220 240 Abundance #92197:1-Pyrenecarboxaldehyde hydrazone 2-4

A 5000 j • ■ ■ ■ । ■ ' ■ ' i ■ ■ ' ■ i ' '

201 38.80 39.00 39.20 39.40 39.60 228 m/z 40.10 34.92% 49 63 100 84 A ,|, 111 , 135 150.163174, ll—ll 122 189 213 O+ 11" • *tI miz—> 20 40 60 80 100 120 140 160 180 200 220 240 Abundance #92199: p-Terphenyl-d14 2-4

38.80 39.00 39.20 39,40 39.60 5000 m/z 121.70 22.28%

127 18 30 42 54 66 80 94 106 136 160172 184 198 212 226 , , 01 ' ' i ' '■'11'1 1 ''' i 111,11T1 il’" 11 r ''1 11" i '■' rt""i '■'■■ i 1 1 ' 1 I"' i ■ ■1 । r । m/z-> Abundance 20 40 60 80 100 120 140 160 180 200 220 240 #92193:1,3-Benzoxazine, 3-methyl-2-phenylimino-perhydro-,„. 2-4 . .. 1... . 38,80 39.00 39.20 39,40 39.60 m/z 245.20 21.83%

5000 106 119 149161 44। 67 93 132 3 55I| hl81 ,YIII , il, 0 1 * I ' ' ‘ 1 I 1 1.. I 1 1 1 1 r1 1 11 1 11 200 i ■ • ■ ■ i * * ■ ■ i ' • ■ ■ i ■ ■ m/z-> 20 40 60 80 100 140 160 180 200 220 240 38.80 39.00 39.20 39.40 39.60

08485.D SCAN020418.M Mon Apr 29 08:31:12 2002 Page 21

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