GCMS calibration data for TCLP method, May 2002

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\1\DATA\MAY0 3 02\9570.D Vial: 44 Acq On 5 May 2002 10:09 am Operator: Sample GC/MS SCAN 4/23 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: May 7 14:49 2002 Quant Results File: GCMS0501.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table ‘ Last Update : Wed May 01 10:40:31 2002 Response via : Initial Calibration

AV V DataAcq Meth : GCMS0501

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-Dichlorobenzene-d4 12.19 152 503220 40.00 ug/1 -0.02 10) Naphthalene-d8 15.83 136 1840288 40.00 ug/1 -0.02 17) Acenaphthene-diO 21.13 164 993490 40.00 ug/1 -0.02 30) Phenanthrene-diO 25.58 188 1386184 40.00 ug/1 -0.02 38) Chrysene-dl2 33.63 240 854772 40.00 ug/1 -0.03 44) Perylene-dl2 37.87 264 557355 40.00 ug/1 -0.02

System Monitoring Compounds 28) TCMX 23.27 209 24938 5.16 ug/L -0.02 Spiked Amount 10.000 Recovery = 51.60% Target Compounds Qvalue 2) N-nitroso-dimethyl amine 0.00 74 0 N.D. 3) bis(2-Chloroethyl)ether 11.46 93 1648 N.D. 4) 1,3-Dichlorobenzene 0.00 146 0 N.D. 5) 1,4-Dichlorobenzene 0.00 146 0 N.D. 6) 1,2-Dichlorobenzene 0.00 146 0 N.D. 7) 2,2'-oxybis(1-Chloropropan 0.00 45 0 N.D. 8) N-Nitroso-di-n-propylamine 0.00 70 0 N.D. 9) Hexachloroethane 0.00 117 0 N.D. 11) Nitrobenzene 0.00 77 0 N.D. 12) Isophorone 14.53 82 14847 0.46 ug/1 98 13) bis(2-Chloroethoxy)methane 15.20 93 356 N.D. 14) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 15) Naphthalene 15.88 128 582 N.D. 16) Hexachlorobutadiene 0.00 225 0 N.D. 18) Hexachlorocyclopentadiene 0.00 237 0 N.D. 19) 2-Chloronaphthalene 19.40 162 181 N.D. 20) Dimethylphthalate 20.48 163 1392 N.D. 21) 2,6-Dinitrotoluene 0.00 165 0 N.D. 22) Acenaphthylene 0.00 152 0 N.D. 23) Acenaphthene 21.23 153 311 N.D. 24) 2,4-Dinitrotoluene 0.00 165 0 N.D. 25) Diethylphthalate 22.61 149 3004 N.D. 26) 4-Chlorophenyl-phenylether 22.76 204 307 N.D. 27) Fluorene 22.76 166 505 N.D. 29) Azobenzen/ 1,2-Diphenylhyd 0.00 77 0 N.D. 31) N-Nitrosodiphenylamine 0.00 168 0 N.D. 32) 4-Bromophenyl-phenylether 0.00 248 0 N.D. 33) Hexachlorobenzene 0.00 284 0 N.D. 34) Phenanthrene 25.64 178 2336 N.D. (#) = qualifier out of range (m) = manual integration 9570.D GCMS0501.M Tue May 07 14:50:30 2002 Page 1

NYC-WTC_000023055