GCMS calibration data for TCLP method, May 2002

NYC 9/11 Public Portal Document

Data File C : \HPCHEM\1\DATA\MAY03 02 \LBC . D vial: 39 Acq On 5 May 2002 5:15 am Operator: Sample GC/MS SCAN 4/23 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 Cyclopentasiloxane, decamethyl Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

14.80 5.22 ug/1 478104 Naphthalene-d8 15.82

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Cyclopentasiloxane, decamethyl- 370 C10H3005Si5 000541-02-6 72 2 Benzene hanamine, N- (pentafluorop 563 C24H34F5NO3Si3 055429-13-5 37 3 Benzoic acid, 2,4-bis (trimethylsil 370 C16H30O4Si3 010586-16-0 37 4 Benzoyc acid, 2,6-bis (trimethylsil 370 C16H30O4Si3 003782-85-2 33 Abundance 7 Scan 1065 (14.796 min): LBC.D (-) m/ z 73.10 100.00% 73

5000 267 355 . .... ................ 45 14.40 14.60 14.80 15.00 15.20 i । ■ ■ ■ i 1 ’ . 99.125.154 193.223 + . 1 293.323 ......... . m/z 267.05 34.81% mz-> 50 100 150 200 250 300 350 400 450 500 550 Abundance #51266: Cyclopentasiloxane, decamethyl- 73

5000 267 355 .mm 14.40 14.60 14.80 15.00 15.20 m/z 355.10 32.28% 207 | 323 1 1 1 1 ' ————————— Tnnu । । । i‘ । 'i m/z-> 50 100 150 200 250 300 350 400 450 500 550 Abundance #74706: Benzeneethanamine, N-[(pentafluorophenyl)methyIene] 73 355

14.40 14.60 14.80 15.00 15.20 5000 m/z 356.10 11.44%

45 208 251 281 -- TTPTTTT ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ 1 386 458 ........548 m/z-> 50 100 150 200 250 300 350 400 450 500 550 Abundance 73 #73975: Benzoic acid, 2,4-bis[(trimethylsilyl)oxy]-, trimet 1 i ■ ■ —ri.... 11 14.40 14.60 14.80 15.00 15.20 m/z 268.05 9.03% 5000 355 45 133 193 223 281 TI———m99-m—mmr ------ m/z—> 50 100 150 200 250 300 350 400 450 500 550 14.40 14.60 14.80 15.00 15.20

LBC.D GCMS0501.M Tue May 07 15:03:32 2002 Page 2

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