GCMS analysis results, sample AE09155, May 2002

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Library Search Compound Report

Data File : C:\MSDCHEM\l\DATA\050902\9155.D Vial: 20 Acq On : 10 May 2002 7:36 am Operator: Mclean Sample : 5/8 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 6 Manganese, .pi.-cyclopentad... Concentration Rank 8

R.T. EstConc Area Relative to ISTD R.T. 30.97 0.41 ug/L 348756 Chrysene-dl2 30.80

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 Manganese, .pi.-cyclopentadienyl... 212 C12H13Mn 001294-94-6 9 2 Benzamide, N-(3-aminophenyl)- 212 C13H12N2O 016091-26-2 5/ 3 4,4’-Diaminobenzophenone 212 C13H12N2O 000611-98-3/5 4 1-Pentanone, 1,3-diphenyl- 238 C17H180 1000164-90-7 5 Abundance Scan 4748 (30.976 min): 9155.D (-4746) (-) m/z 120.30 100.00% 120

5000 104 212 36 49 238 92 30.60 30.80 31.00 31.20 31.40

"n/z-> O'. .. i " 20 1 40 60 80 100 m/z 118.10 61.07%| 120 140 160 180 200 220 240 Abundance #53881: Manganese, .pi.-cyclopentadienyl(toluene)- 120 55

5000 212 30.60 30.80 31.00 31.20 31.40 m/Z 104.10 43.62%| 26 39 n/z-> 0- T-r-f-n- 20 40 +66.80,41106,4 60 80 139 152 186 199 1 ' i ' 1 1 ■ i ' ■ ' • i 1 1 ' 1 I 1 ' 100 120 140 160 180 200 220 240 Abundance #54004: Benzamide, N-(3-aminophenyl)- 120 ..................................................... 92 30.60 30.80 31.00 31.20 31.40 5000 m/z 212.00 35.91%| 212 65 39

miz-> 0- 1728.4,51, 20 40 60 80 77 ITr 100 ,106 ,| 120 166 182193 ■ ■ । 1 1 1 1 । 1‘1 1 ■ । * 1 140 160 180 200 । 1 ■ 1 i 1 1 1 1 i 1 1 220 240 Abundance #54259:4,4'-Diaminobenzophenone 120 30.60 30.80 31.00 31.20 31.40 m/z 36.00 28.86%| 5000 212 92 65

m/z—> 39 18 1 52 ,, 77 0 — r । • । rr’i ~i-i 1"", '"'"I ' r 20 40 60 80 100 — । 139 156167 183 196 120 140 160 180 200 220 240 L ■ i ‘ ■ , ..... I ' ■ i ■ ■ ■ ' I 1 11 1 1 1 30.60 30.80 31.00 31.20 31.40

9155.D 050102.M Mon May 13 11:41:47 2002 Page 9

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