GCMS results for sample AE11426, May 29, 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\020521\11426.D Vial: 12 Acq On : 21 May 2002 7:14 pm Operator: Nefliu Sample : sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: rteint.e

Quant Method : C:\MSDCHEM\1\METHODS\SCAN020521.M (RTE Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1

Peak Number 2 2-Imino-3-methyl-6-nitroben. .. Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T. 28.90 0.21 ug/1 23673 Phenanthrene-dl0 31.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 2-Imino-3-methyl-6-nitrobenzothi... 209 C8H7N3O2S 1000224-45-3 9 2 Dibenzo[b,f]thiepin 210 C14H10S 000257-13-6 9 3 4-Benzoyl-N-(3-methyl-6-nitroben... 417 C22H15N3O4S 1000224-08-0 9 4 5-Bromo-7-methylisatin 239 C9H6BrNO2 1000226-05-2 9 Abundance Scan 4394 (28.896 min): 11426.D (-4388) (-) m/z 208.90 100.00% 209 244 136 5000 86 51 10 181 -P7l ........ 28.60 28.80 29.00 29.20 0 TTTIT i'1 ‘11'1" ’I TT "T m/z 243.90 70.22% niz-> 40 60 80 100120140160180200220 240260280300320340360380400420 Abundance #85194:2-Imino-3-methyl-6-nitrobenzothiazoline 36 209

5000 63 4 1’I’ 1 1 i 1 1 28.60 28.80 29,00 29.20 95 163 181 135 m/z 207.00 69.55%

0 . Mylykoduhsz l+ i11 i" " i" ■ • i" " i11" r1 m/z-> 40 60 80 100120140160180200220240260280300320340360380400420 Abundance #85292: Dibenzo[b,f thiepin 209 178 1A 28.60 28.80 29.00 29.20 5000 m/z 242.10 61.46% 39 104 62 81 I 139

niz-> 0- MMM4, ■I, ill ‘■I'H.p.ljjTrl 4 ’LuITIIITTTTTCIII 40 60 80 100120140160180200220240260280300320340360380400420 Abundance #85207:4-Benzoyl-N-(3-methyl-6-nitrobenzothiazol-2(3H)-yl... ‘ ' i ■ ' ' ' i ■ 209 28.60 28.80 29.00 29.20 m/z 135.90 52.36% 63 5000 95 39 163181 135

n/z—> 0 —ll + 236 283 417 1111 ‘' i'"1111'' i11'' i' ■1' i ■ ■ ‘' i11'11111 40 60 80 100120140160180200220240260 280 300 320 340 360 380 400 420 ■■ ....4 28.60 28.80 29.00 29.20

11426.D SCAN020521.M Fri May 24 09:28:41 2002 Page 4

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