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GC/MS analysis results for sample AD30705, Jan 28 2002

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Laboratory report documenting gas chromatography mass spectrometry results for sample AD30705 conducted on January 28, 2002.

NYC-WTC_000018605–000018623

Folder label: “GCMS X 12/19/01 A 1/2/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File C: \HPCHEM\ 1 \DATA\DEC3101\30705.D Vial: 46 Acq On 2 Jan 2002 9:30 am Operator: 209 GALOS Sample gems scan 12/19a Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 6 Benzeneethanamine, N-[(pentaf1 Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T.

22.80 1.07 ug/1 328226 Phenanthrene-dl0 24.99 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Benzeneethanamine, N-[(pentafluorop 563 C24H34F5NO3Si3 055429-13-5 38 2 N-(Trifluoracetyl)-0,0’,O‘-tris(tri 495 C20H36F3NO4S13 000000-00-0 35 3 Benzoic acid, 2,5-bis (trimethylsilo 370 C16H30O4Si3 003618-20-0 25 4 Trisiloxane, 1,1,1,5,5<5-hexamethyl 384 C12H3604Si5 003555-47-3 25 Abundance Scan 1934 (22.796 min): 30705.D (-) m/z 73.00 100.00% 73

5000 147 355 221 281 45 249. [ 327 401 22.40 22.60 22.80 23.00 23.20 ;m/z~> 1 nh504 ' 100117..n Fi150■ ■ ■■191. t 200 ahnahris 250 300 350 400 450 500 550 m/z 147.00 26.24% Abundance #74706: Benzeneethanamine, N-[(pentafluorophenyl)methylene] I3 355

5000 i1 ■ • • । ■ 22.40 22.60 22.80 23.00 23.20 45 m/z 355.OS 25.79% I 208 251 281 386 458 548 m/z-> ' 50 ' ' 166 '156 266 250 300 350 ‘400 450 500 ′ 530′ Abundance #58807: N-(Trifluoracetyl)-O>O'.O”-tris(triinettiylsilyl)epin 73 355 1***1+**+}*’’I4***I*$ 22.40 22.60 22,80 23.00 23.20 5000 m/z 221.05 19.62%

! 45 j -— 140 184 281 480 ' 1 i ■ ■ • • i • • ■ ■ i ■ ■ • ' i ■ ■ • ■ i ■ ■ ■ ■ ) ‘ t ■ f' 111 I miz-> 50 100 150 200 250 300 350 400 450 500 550 .................... .... ................. ........... Abundance #73978: Benzoic acid. 2,5-bis(trimethylslloxy)-, trimethyls 73 22.40 22.60 22.80 23.00 23.20 355 m/z 281.00 15.91% 5000 45 147 179 223, 267 297 • • i • ■ • • i • ■ • ‘1 ■ ' ‘ ' l‘ 1 ' 1 1 11 r1Tr ■ i ' 1 ■ ' i ■ ' ■ ■ 1 ■ ■ • ■ i • ■ ■ ■ 1 ■ ■ m/z-> 50 100 150 200 250 300 350 400 450 500 550 22.40 22.60 22.80 23.00 23.20

30705.D GCMS1126.M Fri Jan 25 11:27:20 2002 Page 6

NYC-WTC_000018617

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NYC-WTC_000018617Source: NYC Law Department, mirrored locally

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