GCMS analytical comments for sample AD31434, Feb 2002

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Library Search Compound Report

Data File : C: \HPCHEM\ 1 \DATA\JAN1 60231434.D Vial: 21 Acq On : 17 Jan 2002 7:11 am Operator: 209 GALOS Sample : gc/ms scan 12/28 Inst : GC/MS 209 Misc : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0103.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 1 3-Pentanol, 3-methyl- Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

7.45 4.02 ug/1 1002690 1,4-Dichlorobenzene-d4 11.50

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 3-Pentanol, 3-methyl- 102 C6H140 000077-74-7 28 2 1-Butanamine, 3-methyl- 87 C5H13N 000107-85-7 9 3 N-Ethylformamide 73 C3H7NO 000627-45-2 9 4 1,3-Dixolane, 2-methyl - 88 C4H802 000497-26-7 9 Abundance Scan 262 (7.452 min): 31434.D (-) m/z 73.00 ’ 100.00% 73

5000 43 1 i' ‘ ' 1 i ■ ■ ■ ■ i ' ‘

33 |, | 50 55 , 67, । 87 103 7.20 7.40 7.60 7.80 7 t । i i i i । j » i i । j j i I | I ! h 1—!—t—i—j |11 4— r • i ■ • ■ • i 1 J f > ■ ■ । । i ■ m/z 43.00 31.82% m/z-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #63573: 3-Pentanol, 3-methyl- 73

5000 nmmmnDTRTTTTT 7.20 7.40 7.60 7.80 55 m/z 45.05 11.80% „ 45 27,39*.... ..... . , ,...... J87..................... ‘ • l 1 • ' ■ I ' ■ ‘ ‘ I ‘ ‘ I • I ‘ ‘ 3 Tj Tu I I J I 4* | ! I J "I t ill | | I miz-> 10 20 30 40 50 60 70 80 90 100 110 Abundance ■ 0 imiene s-methyl- 30 1 ' s r> r. I ] . . I I | 11"7 [ 1 1 ■ 7.20 7.40 7.60 7.80 5000 m/z 41.05 11.72%

15 •41 55 70 87 ! ‘ ' I ‘ ‘ I ‘ ‘ ' i ‘ ‘ ‘ ‘ I ' ' ' 1 I ‘ ‘ I ' ' ‘ ‘ i ‘ ' 1 I 1 I ' lT'T'1 I | I I I I | i 1 m/z-> 10 20 30 40 50 60 70 80 90 100 110 m pin Abundance #292: N-Ethylformamide 30 7.20 7.40 7.60 7.80 73 m/z 71.00 6.80% 5000 44 58

15 - 1 i 1 1 I ' ' 1 ■ I ' 1 I J J J —1 I J 1 I r I" I' l * * i • * 1113 . । rr miz-> 10 20 30 40 50 60 70 80 90 100 110 7.20 7.40 7.60 7.80

31434.D GCMS0103.M Thu Feb 07 12:37:02 2002 Page 1

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