GCMS reference material results, Dec 2001

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\1\DATA\DEC3101\CAL4 0.D Vial: 2 Acq On 31 Dec 2001 11:56 am Operator: 209 GALOS Sample Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Dec 31 16:03 2001 Quant Results File: GCMS1126.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri Dec 28 15:11:00 2001 Response via : Initial Calibration DataAcq Meth : GCMS1126

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 11.68 152 941271 20.00 ug/1 -0.02 10) Naphthalene-d8 15.29 136 3657710 20.00 ug/1 -0.02 17) Acenaphthene-diO 20.57 164 1756151 20.00 ug/1 -0.01 29) Phenanthrene-diO 24.99 188 2662182 20.00 ug/1 0.00 38) Chrysene-dl2 33.03 240 1727666 20.00 ug/1 0.00 44) Perylene-dl2 37.13 264 1077987 20.00 ug/1 0.00

System Monitoring Compounds 37) 2,4-DDD 29.90 235 20907 0.71 ug/mL -0.17 Spiked Amount 5.000 Recovery = 14.20%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.44 74 1928246 46.58 ug/1 # 77 3) bis(2-Chloroethyl)ether 11.12 93 2788056 42.91 ug/1 91 4) 1,3-Dichlorobenzene 11.58 146 2671779 39.03 ug/1 98 5) 1,4-Dichlorobenzene 11.72 146 2709948 39.15 ug/1 98 6) 1,2-Dichlorobenzene 12.24 146 2481542 38.87 ug/1 98 7) 2,2'-oxybis(1-Chloropropan 12.58 45 4340164 52.45 ug/1 96 8) N-Nitroso-di-n-propylamine 12.98 70 1866745 50.43 ug/1 90 9) Hexachloroethane 13.07 117 1122307 44.57 ug/1 89 11) Nitrobenzene 13.37 77 2874887 0.43 ug/1 # 86 12) 1sophorone 14.02 82 5094864 46.39 ug/1 93 13) bis(2-Chloroethoxy)methane 14.71 93 3249330 44.03 ug/1 99 14) 1,2,4-Trichlorobenzene 15.19 180 2050354 38.60 ug/1 99 15) Naphthalene 15.35 128 6968835 39.87 ug/1 99 16) Hexachlorobutadiene 15.89 225 1051317 40.62 ug/1 99 18) Hexachlorocyclopentadiene 18.07 237 403714 31.91 ug/1 97 19) 2-Chloronaphthalene 18.84 162 3923571 39.16 ug/1 95 20) Dimethylphthalate 19.96 163 4544719 38.94 ug/1 100 21) 2,6-Dinitrotoluene 20.17 165 1090864 39.56 ug/1 # 59 22) Ac enapht hylene 20.10 152 5533751 39.30 ug/1 100 23) Ac enapht hene 20.67 153 3936630 39.10 ug/1 100 24) 2,4-Dinitrotoluene 21.35 165 1415724 40.38 ug/1 # 79 25) Diethylphthalate 22.10 149 4541382 42.05 ug/1 98 26) 4-Chlorophenyl-phenylether 22.22 204 1855433 39.35 ug/1 95 2 7) Fluorene 22.18 166 4020047 38.91 ug/1 98 28) Azobenzen/ 1,2-Diphenylhyd 22.69 77 5728469 51)34 ug/L # 89

(#) = qualifier out of range (m) = manual integration CAL40.D GCMS1126.M Mon Dec 31 16:04:13 2001 Page 1

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