GCMS calibration log sample AD29289, Dec 2001

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\l\DATA\DEC1201\CAL40.D Vial: 2 Acq On 12 Dec 2001 11:46 am Operator: 209 GALOS Sample Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Dec 12 14:21 2001 Quant Results File: GCMS1126.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed Nov 28 15:06:24 2001 Response via : Initial Calibration DataAcq Meth : GCMS1126

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 11.69 152 1736720 20.00 ug/1 -0.01 10) Naphthalene-d8 15.30 136 6759377 20.00 ug/1 -0.01 17) Acenaphthene-diO 20.56 164 3240719 20.00 ug/1 -0.01 29) Phenanthrene-diO 25.00 188 5174739 20.00 ug/1 0.00 38) Chrysene-dl2 33.04 240 3424401 20.00 ug/1 0.00 44) Perylene-dl2 37.13 264 2405284 20.00 ug/1 0.00

System Monitoring Compounds 37) 2,4-DDD 30.06 235 711 0.01 ug/mL -0.01 Spiked Amount 5.000 Recovery = 0.20%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.42 74 3516095 46.03 ug/1 97 3) bis(2-Chloroethyl)ether 11.14 93 4850190 40.46 ug/1 98 4) 1,3-Dichlorobenzene 11.59 146 4810115 38.08 ug/1 99 5) 1,4-Dichlorobenzene 11.73 146 4726517 37.01 ug/1 99 6) 1,2-Dichlorobenzene 12.25 146 4249514 36.08 ug/1 98 7) 2,2'-oxybis(1-Chloropropan 12.58 45 6524884 42.74 ug/1 99 8) N-Nitroso-di-n-propylamine 13.01 70 2933069 42.95 ug/1 99 9) Hexachloroethane 13.06 117 1856589 39.96 ug/1 96 11) Nitrobenzene 13.39 77 4353464 41.32 ug/1 99 12) 1sophorone 14.04 82 8419502 41.48 ug/1 98 13) bis(2-Chloroethoxy)methane 14.72 93 5461259 40.05 ug/1 100 14) 1,2,4-Trichlorobenzene 15.19 180 3699063 37.69 ug/1 99 15) Naphthalene 15.36 128 11823194 36.61 ug/1 99 16) Hexachlorobutadiene 15.89 225 1770727 37.02 ug/1 100 18) Hexachlorocyclopentadiene 18.07 237 819633 35.11 ug/1 98 19) 2-Chloronaphthalene 18.85 162 7037110 38.06 ug/1 97 20) Dimethylphthalate 19.98 163 8437849 39.18 ug/1 99 21) 2,6-Dinitrotoluene 20.19 165 2119847 41.66 ug/1 # 66 22) Acenaphthylene 20.11 152 9933237 38.23 ug/1 100 2 3) Acenaphthene 20.68 153 6833365 36.78 ug/1 100 24) 2,4-Dinitrotoluene 21.35 165 2758959 42.64 ug/1 # 91 25) Diethylphthalate 22.12 149 7831694 39.30 ug/1 100 26) 4-Chlorophenyl-phenylether 22.22 204 3124924 35.92 ug/1 97 27) Fluorene 22.19 166 6787220 35.60 ug/1 100 28) Azobenzen/ 1,2-Diphenylhyd 22.69 77 8720393 42.35 ug/L 97

(#) = qualifier out of range (m) = manual integration CAL40.D GCMS1126.M Thu Dec 27 12:22:38 2001 Page 1

NYC-WTC_000036342