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GCMS analysis results for sample AD30426, Jan 2002

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Laboratory report detailing gas chromatography-mass spectrometry analysis of sample AD30426 conducted on January 10, 2002.

NYC-WTC_000017724–000017747

Folder label: “GCMS X 12/13/01 A 12/27/01

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NYC 9/11 Public Portal Document Library Search Compound Report

- Data File : C:\HPCHEM\1\DATA\DEC2701\30426.D Vial: 23 Acq On : 28 Dec 2001 11:28 am Operator: 209 GALOS Sample : GC/MS SCAN 12/13 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator). Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 6 Benzeneethanamine, N-[(pentaf1 Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

22.79 2.70 ug/1 1344980 Phenanthrene-dl0 24.98

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 Benzeneethanamine, N-[(pentafluorop 563 C24H34F5NO3Si3 055429-13-5 37 2 N-(Trifluoroacetyl)-0,0',O''-tris(t 481 C19H34F3NO4Si3 000000-00-0 37 3 Trisiloxane, 1,1,1,5,5,5-hexamethyl 384 C12H3604Si5 003555-47-3 37 4 N-(Trifluoroacetyl)-N,O,O»,O'’-tetr 553 C22H42F3NO4Si4 000000-00-0 35 Abundance Scan 1933 (22.787 min): 30426.D (-) m/z 73.00 100.00% 73

5000 147 355 221 281 ' I ' ■■■ 1 I ' ' ' 1 1 1 ' ■ ■ 1 1 1 45 0- ' 5 • —17 h 191, [ 249, I — 327 : l , 401, 441.., 22.40 22.60 22.80 23.00 23.20 m/z 147.00 26.26% miz-> 50 100 150 ‘ 200 250 300 350 400 450 500 550 Abundance " #74706: Benzeneethanamine, N-K(pentafluoropheny!)methylene] 73 355

I 5000 ■ i * • ' ■ i • ■ 1 1 1 1 ' 1 1 1 1 1 22.40 22.60 22.80 23.00 23.20 m/z 355.0 24.52% 45 208 548 1. ’ I’*’I’ *’I***I** ■ 251.281 — 386 458 m/z--> 50 100 150 200 250 300 350 400 450 500 550 Abundance #58326: N-{Tnfluorcacetyl-0.C’Q"-tris(trimethylsilylno 73 355 22.40 22.60 22.80 23.00 23.20 5000 m/z 221.05 18.25%

45 120147 193 265 481 1 ' I 1 1 1 ■ i ■ ■ ■ ■ I ■ ' ' ■ i ■ ■ ■ ■ i • • ■ • i ‘ ■ i ■ ■ 1 ■ i • ■ ‘ ■ i ■ ■ ■ ■ i ■ • -r-r-|-r-r miz-> 50 100 150 200 250 300 350 400 450 500 550 Abundance #52459: Trisiloxane, 1,1,1,5,5,5-hexamethyl-3,3-bis[(trimet 73 147 22.40 22.60 22.80 23.00 23.20 281 m/z 281.00 14.00% 5000

369 207 249, -- 338 1 111'1 m/z-> 50 100 150 200 250 300 ' 350 400 " 450 '' 500 ' ‘ 550 22.40 22.60 22.80 23.00 23.20

30426.D GCMS1126.M Wed Jan 02 11:08:01 2002 Page 6

NYC-WTC_000017737

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NYC-WTC_000017737Source: NYC Law Department, mirrored locally

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