GCMS quantitation report, May 22 2002

NYC 9/11 Public Portal Document LIbrary aearen compound Report Data File : C:\MSDCHEM\l\DATA\052202\11905.D Vial: 12 Acq On : 22 May 2002 10:47 pm Operator: Mclean Sample : 5/21 ad Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 6 Propiolonitrile Concentration Rank 8 R.T. EstConc Area Relative to ISTD R.T.

3.98 0.62 ug/L 480104 1 ,4-Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual

l Propiolonitrile 51 C3HN 001070-71-9 4 2 Propanoyl chloride 92 C3H5C10 000079-03-8/2 3 Methane, chlorodifluoro- 86 CHC1F2 000075-456 1 4 Methane, chlorodifluoro- 86 CHC1F2 000075-45-6 1 Abundance Scan 153 (3.978 min): 11905.D (-151) (-) m/z 51.10 100.00% 51

84 5000 35 3.60 3.80 4.00 4.20 4.40 0- -P40— +1 ......... । —r 0 m/z 47.10 67.34%

_MMwa. ■ ■ i ■ ■ ■ ■ I 1 1 1 1 I 1 1 1 1 I 1 ■' । ■ ■ ■ ■ ।' ■ ■ ■ । ■ n/z-> 0 10 20 30 40 50 60 70 80 90 100 Abundance #12371: Propiolonitrile 51

5000 3.60 3.80 4.00 4.20 4.40 m/z 84.00 60.04%

miz-> 0- -1218 0 10 20 4,32,4,46, 30 40 50। 1 ■ ■ 1 i ■ ■ ■ ■

60 i ■ ■ ■ ■ i ■ ■ ■ 1 i ■ ■ ■ ■ i ■

70 80 90 100 Abundance #472: Propanoyl chloride 29 57 360 3.80 4.00 4.20 4.40 5000 m/z 35.10 31.44% Aim 0- 42 .1 11, ■ . 24 35 42 49 I I ■ .'I'l-i'b. , 7-| 65 71 76 82 91 i■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ 1 i ■■ 1■ (Wi miz-> 0 10 20 30 40 50 60 70 80 90 100 Abundance #12363: Methane, chlorodifluoro- 51 3.60 3.80 4.00 4.20 4.40 m/z 36.10 27.38%

5000

31 67 13 19 24 || 37 , j ,56,^,....,^............. 0 ' ' i 1 ■ ■ • i 1 ■ ■ ''i ■ ' ' ' i 1 111 1 1 1 1 '1 1 n/z-> 0 10 20 30 40 50 60 70 80 90 100 3.60 3.80 4.00 4.20 4.40

11905.D 052202.M Tue May 28 12:12:04 2002 Page 9

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