GCMS analysis report sample AE09682, May 23, 2002

NYC 9/11 Public Portal Document Library aearen compound keport

Data File : C:\MSDCHEM\l\DATA\052102\9682.D Vial: 18 Acq On : 22 May 2002 3:11 am Operator: Mclean Sample : re-extract Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 3 Propiolonitrile Concentration Rank 7

R.T. EstConc Area Relative to ISTD R.T.

3.79 0.64 ug/L 452999 1,4-Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Propiolonitrile 51 C3HN 001070-71-9 /3 2 Methane, chlorodifluoro- 86 CHC1F2 000075-45-6/ 2 3 Ethanol, l-ethoxy-2,2,2-trifluoro- 144 C4H7F3O2 000433-27-2 1 4 2-p-Nitrobenzoyl-l,3,5-tribenzyl... 569 C33H31NO8 1000129-85-6 1 Abundance Scan 122 (3.796 min): 9682.D (-119) (-) m/z 47.10 100.00%

5000 38 47 84

a/M 58 3.40 3.60 3.80 4.00 4.20 i' . O+ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ I1. > ■ ■ । ■ ■ ■ ■ ।' ■ ■ ■ । ■ ■ ■ ■ । ■' ■ ■ । ■ m/z 84.00 92.80% miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 / Abundance #12371: Propiolonitrile 51

5000 3.40 3.60 3.80 4.00 4.20 m/z 51.10 78.16% /" 0: 25 3 38— 12 12 132+ -18 । ■ i ■ ■ ■ • i ■ ■ ■ • i ■1 ■ ■ i ■ ■ ■ • i ■ ■ ■ ■ i1'11 n '1' i1' nfa->_____ 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #111064: Methane, chlorodifluoro- 51 ‘ I**‘‘I**‘‘I** 3.40 3.60 3.80 4.00 4.20 5000 m/z 38.10 48.39%

67

■n/z-> O+ ,13.24/31,27,43. 10 20 30 40 50 60 .1. 85 1' " i > > 111 1***) ss’l ।, ■ >, । >. .. ।, 111 p 111111 70 80 90 100 110 120 130 Abundance #12277: Ethanol, 1 -ethoxy-2,2,2-trifluoro- —1 47 3.40 3.60 3.80 4.00 4.20 m/z 81.90 39.70% 5000 75 69

m/z-> 0 — —99— .182 99 115 127 ‘I ***4441*4*144**! n- 12114 10 20 30 40 50 60 70 80 90 100 110 120 130 3.40 3.60 3.80 4.00 4.20

9682.D 052202.M Wed May 22 11:46:43 2002 Page 5

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