GCMS analysis report sample AE09517, May 23, 2002

NYC 9/11 Public Portal Document Llprary aearcn compound Report Data File : C:\MSDCHEM\1\DATA\052102\9517.D Vial: 13 Acq On : 21 May 2002 11:07 pm Operator: Mclean Sample : re-extract Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 6 Propiolonitrile Concentration Rank 8 R.T. EstConc Area Relative to ISTD R.T. 3.93 0.97 ug/L 666096 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Propiolonitrile 51 C3HN 001070-71-9 4 2 2-p-Nitrobenzoyl-l,3,5-tribenzyl... 569 C33H31NO8 1000129-85-6 4 3 Pyridazine 80 C4H4N2 000289-80-5 2 4 Ethyl Chloride 64 C2H5C1 000075-00-3 2 Abundance Scan 145 (3.931 min): 9517.D (-143) (-) m/z 51.10 100.00% 51

47 5000 84 35 39 43 ’ 14*’’I*’’I****I*’I 3.60 3.80 4.00 4.20 58 87 01----- TI1UTIT p-rri-p-rrri-rr m/z 47.10 53.13% miz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 30 95 ... Abundance #12371: Propiolonitrile 51

5000 ■ * i ■ ■ 1 ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■ • i 3.60 3.80 4.00 4.20 m/z 84.00 45.10%

niz-> Of .12.,18,..7728,32.,138,..,47 5 10 15 20 25 30 35 40 45 50 55 60.65 70 75 80 85 90 95 ' ' ‘ I ‘‘ 'I ' ‘ ‘ I " " I “ “ I'' ‘ ' I " ' ‘ 1 ‘ " ‘l" ‘ “ I "

Abundance #12372:2-p-Nitrobenzoyl-1,3,5-tribenzyl-alpha.-d-ribose 51 ■ 1 i ■ ■ ■ ■ i • ■ ■ ■ i ' • ■ ■ i ■ ■ ■ ■ i 3.60 3.80 4.00 4.20 5000 m/z 43.10 29.37%

411 45 AAoukt O+ ................ miz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #111060: Pyridazine • ■ i ■' ■ ■ । ■ ■ ■ ■ । ■ ■ • ■ । ■ ■ ■ ■ । 51 3.60 3.80 4.00 4.20 m/z 39.10 24.08% 5000' 26 80 A 37 0: "‘119211—171117771T । ■. । h 111.1111111 > 11 > ।. 111 > I T—mgEmgaamnuT TPT T ■ ■ i 1 • ■ ■ i * • • * i m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.60 3.80 4.00 4.20

9517.D 052202.M Wed May 22 11:29:25 2002 Page 9

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