GCMS analysis report sample AE09679, May 23, 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\052102\9679.D Vial: 17 Acq On : 22 May 2002 2:22 am Operator: Mclean Sample : re-extract Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 5 Propiolonitrile Concentration Rank 6

R.T. EstConc ' Area Relative to ISTD R.T. 3.90 1.29 ug/L 817642 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Propiolonitrile 51 C3HN 001070-71-9 3 2 Ethanol, 2,2,2-trifluoro- 100 C2H3F30 000075-89-8/2 3 Methane, chlorodifluoro- 86 CHC1F2 000075-45-6 1 4 2-p-Nitrobenzoyl-l, 3,5-tribenzyl... 569 C33H31NO8 1000129-85-6 1 Abundance Scan 139 (3.896 min): 9679.D (-138) (-) m/z 51.10 100.00% 51

5000 35 41 84 3.60 3.80 4.00 4.20 । m/z 47.00 43.12% 0+ ■ ■ i ■ • ■ ■ i ■ ■ • ■ i ‘ ■ • । ■ ■ ‘ ■ । ■ ■ ■ ' । ■ miz-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #12371: Propiolonitrile 51 _Mt 5000 3.60 3.80 4.00 4.20 m/z 35.10 38.95% 01 +2,18, 3,32 1 ■ ■ ■ i ■ ' ■ ■ i ■ ■ ' ■ i ■ ■ ■ 1 i 1 ■ ■ 1 i ‘ ' ■ i •

miz-> 10 20 30 40 50 60 70- 80 90 100 110 Abundance #108317: Ethanol, 2,2,2-trifluoro- 31

3.60 3.80 4.00 4.20 5000 m/z 41.10 28.80% 51 61 6% 74 81, 100 niz-> 01 10 14 19 26 . । 20 30। 140,451 40 50 60 70 80 90 100 110 Abundance #12363: Methane, chlorodifluoro- 51 3.60 3.80 4.00 4.20 m/z 84.00 25.18% 5000

31 67 13 19 24 || 37 ———————————————— , , 56 J , 85 0 ■ ■ ■ i ' 1 1 1 i ■ ■ ■ ■ i ‘ '' 1 i ■ ■ ■ • i 1 1 1 1 i 1 n/z-> 10 20 30 40 50 60 70 80 90 100 110 3.60 3.80 4.00 4.20

9679.D 052202.M Wed May 22 11:45:19 2002 Page 8

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