GCMS analysis results, sample AE12533, June 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\052902\12533.D vial: 24 Acq On : 30 May 2002 4:49 am Operator: McLean Sample : gc/ms scan 5/28 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 3 Propiolonitrile Concentration Rank 3 R.T. EstConc Area Relative to ISTD R.T. 3.76 0.93 ug/L 731865 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Propiolonitrile 51 C3HN 001070-71-9 3/ 2 Acetic acid, chloro-, ethyl ester 122 C4H7C1O2 000105-39-5 2 3 Methane, chlorodifluoro- 86 CHC1F2 000075-45-6 2 4 Boron trifluoride etherate 142 C4H10BF3O 000109-63-7 1 Abundance Scan 116 (3.761 min): 12533.D (-111) (-) m/z 51.10 100.00% 51

5000 86 36 43 340 3.60 3.80 4.00 4.20 ----- m/z 4 9.. 10 89.33% O+ • i ■ ■ ' ■ i ■ ■ • ‘ i ■ • I ■1 ■ • i ■ ■ ■ 1 i ■ ‘ 1 • i ‘ ■ i • miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #12371: Propiolonitrile 51

5000 3.40 3.60 3.80 4.00 4.20 m/z 86.00 37.77%

niz-> ol -P Abundance 10 12 . 20 25 38 18—432 11sk-*******1* 29 30 40 50 60 70 80 90 100 #108005: Acetic acid, chloro-, ethyl ester 110 120 130 _/a 3.40 3.60 3.80 4.00 4.20 5000 m/z 43.10 26.77% 77 42 49 14

tnfz-> 01 - 10 20 30 35—40 L+4 50 59 65 | 88 94 107 T!r 1HITPTTTTITITTI 122 60 70 80 90 100 110 120 130 Mw Abundance #111064: Methane, chlorodifluoro- 51 340 3.60 3.80 4.00 4.20 m/z 36.10 21.84% 5000

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m—s 0 .131/24/31,27,43 10 20 30 40 50 .1. 85 1TT ‘ 1 ' ■ 1 1 1 1 * ‘ ‘ | t i'l l । . . . . । , , , , । ■ . . , ] . . . . ) , 60 70 80 90 100 110 120 130 3.40 3.60 3.80 4.00 4.20

12533.D 052202.M Mon Jun 03 11:45:25 2002 Page 6

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