GCMS surrogate recovery results, sample AE12326, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\052902\12326.D Vial: 17 Acq On : 29 May 2002 11:07 pm Operator: McLean Sample : gc/ms scan 5/28 Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 3 Propiolonitrile Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

3.84 1.71 ug/L 1094280 1,4-Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW Mol Form CAS# Qual

1 Propiolonitrile 51 C3HN 001070-71-9 3 2 Pent-4-enylamine 85 C5H11N 022537-07-1 2 3 2-Butyne-1,4-diol, diformate 142 C6H604 036677-73-3 2 4 Methane, chlorodifluoro- 86 CHC1F2 000075-45-6 1 Abundance Scan 130 (3.843 min): 12326.D (-129) (-) m/z 51.10 100.00% / 51

5000 42 88

36 3.40 3.60 3.80 4.00 4.20 0- 120..... Il 40Jill .1.150 ‘ 60I4+11++‘*114 1 ‘ ‘ 1 I ’ ' * ‘ I ‘ ' i 1 ‘‘ ‘ I * ‘ m/z 47.10 66.67% miz->______ 10 Abundance 30 70

51 80 90 100 110 120 130 #12371: Propiolonitrile Wy 5000 3.40 3.60 3.80 4.00 4.20 m/z 42.05 42.55% 12 .25 . 38 01 -18 ■ 1, 32 Hl-.... 1 ■ ■ • i ■ ■ ■ ' i • ■ ■ ■ i ■ ■ ■ ■ i ■ • ■ ■ i • • ■ ■ i ‘ • i ■ ■ ■ ■ 11 ■

m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #745: Pent-4-enylamine 33

3.40 3.60 3.80 4.00 4.20 5000 m/z 88.00 40.65% 43 56 01 - 43741 THgamun—mpdu 84 50, | —2**OI_UI1UT h

m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #381:2-Butyne-1,4-diol, diformate 29 39 3.40 3.60 3.80 4.00 4.20 m/z 43.10 37.13% 5000

m/z—> 0, ... r • 1+— W144 -1 10 18

20 ,,, 76 30 86 40 97 W5 113 51

50 125 ,58

60 68

70 80 90 100 110 120 130 y’w 3.40 W. 3.60 3.80 4.00 4.20

12326.D 052202.M Mon Jun 03 11:32:48 2002 Page 6

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