GCMS quantitation report, May 22 2002

NYC 9/11 Public Portal Document Llbrary searen compound keport

Data File : C:\MSDCHEM\1\DATA\052202\11905.D Vial: 12 Acq On : 22 May 2002 10:47 pm Operator: Mclean Sample : 5/21 ad Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan *= Library- : C:\DATABASE\NIST98.L Peak Number 5 Propiolonitrile Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T.

3.89 1.20 ug/L 926280 1,4-Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Propiolonitrile 51 C3HN 001070-71-9 3 •2 Ethanol, 2,2,2-trifluoro- 100 C2H3F30 000075-89-8 1 3 Ethanol, 2,2,2-trifluoro- 100 C2H3F3O 000075-89-81 4 2-p-Nitrobenzoyl-1,3,5-tribenzyl... 569 C33H31NO8 1000129-85-6 1 Abundance Scan 138 (3.890 min): 11905.D (-137) (-) m/ z 49.10 '00.00% 49 84

5000 38

44

H40 L 50 3.60 3.80 4.00 4.20 0! • • । ■ • • ’ । • • • ■ । • 1 ■ ' i' ■ • ■ i 1 • ■ ■ i ■ ■ ' ■ i 1 m/z 51.10 97.62% niz-> 10 20 30 60 70 80 90 100 /. Abundance #12371: Propiolonitrile 51

5000 3.60 3.80 4.00 4.20 m/z 84.00 86.94% 12 . 25 38 * ol —18.11/-32,11/1,46.1 ' ■ ■ ' i ' ■ ■ ■ i ■ ■ ■ 1 i ■ ■ ■ ■ i ■ ■ ■ 1 i • • ■ ■ i

miz-> 10 20 30 40 50। 60 70 80 90 100 Abundance #108313: Ethanol, 2,2,2-trifluoro- 31&

3.60 3.80 4.00 4.20 5000 m/z 38.00 47.03 61 51 y 13 19 26 44 69 . 81 100 0 +1 1 illi 111 ■ ' i ■ ■ ■ ri 1 1 1 1 r i । i i—r-1-] । i i i j miz-> 10 20 30 40 50 60 70 80 90 100 Abundance #108306: Ethanol, 2,2,2-trifluoro- 31 3.60 3.80 4.00 4.20 m/z 82.95 19.71% 5000

0- ........ 26 . 44 „ ■ ■ i 1 ■ ' 1 1 1 1 1 1 1 ।1 1 1 ■ 1 ■•■T‘ ■ 1 ' I1''1 "Y " 69 8 ,1 । 99। ■ ■ ■ ■ । miz-> 10 20 30 40 50 60 70 80 90 100 3.60 3.80 4.00 4.20

11905.D 052202.M Tue May 28, 12:12:01 2002 Page 8

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