GCMS analysis results for unknown compounds, June 2002

NYC 9/11 Public Portal Document LLLY DCaLtil topoulU RCDOL L

Data File C:\MSDCHEM\1\DATA\060702\12738.D Vial: 14 Acq On 7 Jun 2002 7:10 pm Operator: Sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 7 l-Buten-3-yne, 2-chloro- Concentration Rank 6 R.T. EstConc Area Relative to ISTD R.T.

4.30 2.69 ug/L 1563160 1,4-dichlorobenzene-d4 9.89

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1■l-Buten-3-yne, 2-chloro- 86 C4H3C1 017712-36-6 9 2 4-Chlorobuten-3-yne 86 C4H3C1 040589-38-69 3 l-Buten-3-yne, 1-chloro-, (Z) - 86 C4H3C1 020374-90-7 7 4 1,2,3-Butatriene, 1-chloro- 86 C4H3C1 020658-21-3 7 Abundance Scan 207 (4.296 min): 12738.D (-205) (-) m/z 86.00 /100.00% 85

51 5000 42 47 37 70 83 4.00 4.20 4.40 4.60 0- - 11 ■ ■ ■ । ■ J ----- —PPP m/z 51.05 58.26% miz-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #34744:1-Buten-3-yne, 2-chloro- 51 86

5000

01 ■ • i ■1 • • i • ■ ■ ■ i • ■ ■ ■ i ■ ■ 60 1 ■ > i"' ■ 1 ■"' i “ “ i"1111 “' i “ ■11 39 f i > > i । i i "WhWMw] 4.00 4.20 4.40 4.60

niz-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12405: 4-Chlorobuten-3-yne 51 86

4.00 4.20 4.40 4.60 5000 m/z ", 50.05 35.91%

60

m/z-> 0- 30 35 40 45 . 4851 IA90—PP 50 55 60 65 70 75 80 95 Abundance #111070:1-Buten-3-yne, 1-chloro-, (Z)- 51 86 4.00 4.20 4.40 4.60 ' m/z 49.10 32.20%

5000

60 n/z-> 0 ■ i ■ ■ ■ . j • ■ ■ > । 30 35 40 * i i i । tt 45 - ' 1 " " 11 “ 111' " I “ " 1 50 55 60 65 70 75 80 85 IP990.. 95 4.00 4.20 4.40 4.60

12738.D 060302.M Mon Jun 10 11:45:37 2002 Page 10

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