GCMS analysis results, sample AE12478, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\052902\12478.D Vial: 20 Acq On : 30 May 2002 1:34 am Operator: McLean Sample : gc/ms scan 5/28 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number.15 Phenanthrene, 9-methyl- Concentration Rank 15 R.T. EstConc Area Relative to ISTD R.T. 22.54 0.26 ug/L 284747 Phenanthranene- dl 0 22.91 Hit# of 5 Tentative ID MW MolForm CAS# Qual 9 1 Phenant hrene, 9-methyl- 192 C15H12 000883-20-5 59 2 Thiocyanic acid, 2-benzothiazoly... 192 C8H4N2S2 006011-99-0 59 3 2,4-Diamino-6-(hydroxymethyl)pte... 192 C7H8N60 000945-24-4 59 4 2,4-Diamino-6-(hydroxymethyl)pte... 192 C7H8N60 000945-24-4 59 Abundance Scan 3311 (22.533 min): 12478.D (-3305) (-) m/z 192.10 100.00% 192

5000

42 51 70 82 96 118 146 160 ' 1 I ‘ ‘ 1 • I 4 ' ‘ ’ I J 22.20 22.40 22.60 22.80 A ‘ ‘ I 1 • ’ ’ I

04mTTTHTmTTTTT , , , ‘ h"mH . 11" m/z 146.10 16.81% n/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #81033: Phenanthrene, 9-methyl- 1912

5000 22.20 22.40 22.60 22.80 0 m/z 191.10 15.61% 29 39 51 63 74 83 T 115 126 139 152 165 176 J, | 0’ • I " " I ‘' rl " " I " 111 ‘‘‘ ri I 1 i'I'i rt 111! 11 f > i 111 ri ip ■ i > । i i 11'| 1111 rtu 111 Pl'i 111 rl 111 111" miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80870: Thiocyanic acid, 2-benzothiazolyl ester 15/2

22.20 22.40 22.60 22.80 ‘ 5000 m/z 193.00 11.22% 69 109 45 । | 90 18 134 148 160 qp m t I । I | l t I I । l t I t | ) ! I |-| I t I 122 111 l-i i । > 1111 > 11111 i'l i p-n 1111 i rf 1..... Ot - 1′1’ m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80958:2,4-Diamino-6-(hydroxymethyl)pteridine .......... l ‘ ’ I * ‘ ' I ’ ‘ ' I ' * ' ’ I ’ 1 ' ‘ I 43 163 192 22.20 22.40 22.60 22.80 m/z 96.10 11.08% 5000 28 53 68 .. 146 176 92 106 121 133

n/z—> O ml Hpl+7HIlLt■i ■ ■ Ah i i-l'l-!... A ,, T , ■ ■ h ,, ml. 114 , i 77

20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 ‘It ' 1 i ' 1 1 ■ i ■ ■ i ■ 1 ■ ‘ i 1 1 •• i 22.20 22.40 22.60 22.80

12478.D 052202.M Mon Jun 03 11:40:45 2002 Page 18

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