GCMS analysis results, sample AE12476, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\052902\12476.D vial: 18 Acq On : 29 May 2002 11:56 pm Operator: McLean Sample : gc/ms scan 5/28 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 16 Phenanthrene, 9-methyl- Concentration Rank 18 R.T. EstConc Area Relative to ISTD R.T.

22.53 0.28 ug/L 317359 Phenanthranene- dl 0 22.91 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 "Phenanthrene, 9-methyl- 192 C15H12 000883-20-5 53 ' 2 Phenant hrene, 1-methyl- 192 C15H12 000832-69-9 42‘ 3 1H-2-Indenone,2,4,5,6,7,7a-hexah... 192 C13H20O 1000196-69-5 42 4 Isoquinoline, 1,2,3,4-tetrahydro. . . 328 C18H20N2O4 1000128-79-2 42 Abundance Scan 3311 (22.533 min): 12476.D (-3305) (-) m/z 192.05 100.00% 192

5000 V

m/z-> O 42 52 70 82 | mpmmpmtmpmmmp] 120 | 160 ,| 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 l—p 22.20 22.40 22.60 22.80 m/z 193.00 16.98% Abundance #81033: Phenanthrene, 9-methyl- 192

5000 ■ ■ । ■ 1 1 1 ■ ■ ■1 11 1 1 1 1 1 1 1 1 1 22.20 22.40 22.60 22.80 m/z 191.10 16.20% 29 39 51 63 74 83 % 115 126 139 152 165 176 I 0 ‘ I " ■ ‘ I' “ ' I “ “ I ‘ ‘ 111111 I-11 rl 111 * 1111111 n * 111111111 rrrri r rtrit I i’t’i 11 ■ rp! 111 i’t)t ‘ 1‘* n/z-> 2030405060 70 8090 100 110 120130140 150160 170 180 190 200 Abundance #125856: Phenanthrene, 1-methyl- 192

22.20 22.40 22.60 22.80 5000 m/z 96.00 14.91%

96 er

niz-> 27 39 51 63 82 olTDWTTTTTTTTTTTTTTTTTTHrt II 115 126 139 152 190 178 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 k Abundance #80945:1 H-2-lndenone,2,4,5,6,7,7a-hexahydro-3-(1-methylet... 192 22.20 22.40 22.60 22.80 m/z 146.10 14.76% 149 177 a 5000 41 93 107 164

+ll 55 67 79 1 121 135 27

/z—> m. I I, ■ Allepallp.. 0 rerytieropromt Pr 20 30 40 50 60 70 80 90 100110 120 130 140 150 160 170 180 190 200 ----A 22.20 22.40 22.60 22.80

12476.D 052202.M Mon Jun 03 11:34:19 2002 Page 19

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