GCMS analysis results, sample AE12323, June 2002

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Data File : C:\MSDCHEM\l\DATA\052902\12323.D Vial: 11 Acq On : 29 May 2002 6:14 pm Operator: McLean Sample : gc/ms scan 5/24 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 3 Propiolonitrile Concentration Rank 7 R.T. EstConc Area Relative to ISTD R.T.

3.73 0.85 ug/L 549617 1,4-Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Propiolonitrile 51 C3HN 001070-71-9 4 2 l-Buten-3-yne, 1-chloro-, (Z) - 86 C4H3C1 020374-90-7/ 4 3 Methane, chlorodifluoro- 86 CHC1F2 000075-45/6 2 4 Pyrrolidine, 2-ethyl-l-methyl- 113 C7H15N 026158-82-7 2 Abundance

5000 Scan 110 (3.726 min): 12323.D (-108) (-) 51

84 m/z

P 51.10 100.00%

70 3.40 3.60 3.80 4.00 11 •111" “ I'1" i'1" i11" i" " m 01 ■ ‘ i" " i" “ i ■ ■ ■■ i ■ ■ ■1 m" i “ "35i1'"4043 88 HPTP m/z 84.0.0 55.62% n/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 95 Abundance #12371: Propiolonitrile 51

5000 3.40 3.60 3.80 4.00 m/z 86.00 42.38% / miz-> 01 5+12.18,4428,32.4138,4447. 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12406:1-Buten-3-yne, 1-chloro-, (Z)- 51 86 3.40 3.60 3.80 4.00 5000 m/z 70.00 17.14%

26 30 37 43 48 , 0B9—1rt83, 6063 ——7174 01 i. ।..., 11 i ri 11111 11111 |+i n 11 j! 111111 j 111111 tl I 1u9uu!tumu 139 ’i +110910ns miz-> 5 10 15 20253035404550556065 70 75 80859095 Abundance #111064: Methane, chlorodifluoro- • ■ i ' ■ ' 1 i ■ ■ l ■ ■ ■ ■ । • I 51 3.40 3.60 3.80 4.00 rn/z 84.90 7.24% 5000

67 13 19 24 2831 3538 43 47, 0- TpPTpt I ■: 111 > 1111 ii 1 , 8588 1111111111111.111111 ( I n ] 11111111

/z—> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.40 3.60 3.80 4.00

12323.D 052202.M Mon Jun 03 10:50:43 2002 Page 6

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