GCMS blank results for VOCs, sample AE12326, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\052902\LBA.D Vial: 14 Acq On : 29 May 2002 8:41 pm Operator: McLean Sample : gc/ms scan 5/28 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 5 Propiolonitrile Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T. 3.81 1.11 ug/L 657460 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Propiolonitrile 51 C3HN 001070-71-9 4 2 l-Buten-3-yne, 1-chloro-, (Z)- 86 C4H3C1 020374-90-7/4 3 l-Buten-3-yne, 1-chloro-, (Z)- 86 C4H3C1 020374-90-7 2 4 1,2,3-Butatriene, 1-chloro- 86 C4H3C1 020658-21-3 2 Abundance Scan 124 (3.808 min): LBA.D (-123) (-) m/z 51.10 100.00%

′"Yw 51

5000 53 38 8588 I44 ‘ * 1 42 3.40 3.60 3.80 4.00 4.20 01 ■'i■1■■ i■ ■ ■ ■ i■ “'i■ ■"i•"•i"i'' 35 • • ■ । ■ ■ ■ ■ ।' “ ■ । • ■ ■ ■ । • ‘' • i • ■' ■ । ■ ■1 ■ m/z 38.00 27.82% ’I’4441848 m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12371: Propiolonitrile 51

5000 - 3.40 3.60 3.80 4.00 4.20 m/z 87.90 27.33%

niz-> 01

Abundance 5 „12.,,18,.7728,32,,138,....,47. 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 ।‘ ।

#12406:1-Buten-3-yne, 1-chloro-, (Z)- 51 । ■1 ■ । ■ ■ ■ ■ । । । ■i•■•■।

86 ”i“•

M../hH-ws 3.40 3.60 3.80 4.00 4.20 5000 m/z 84.95 22.55%

mfe~> ol-ri f.u . 11 26 30 37 43 48 ...................................... . r> IH 1111 > i > 1111 [ 1 • 11 j 11111 H f 11»»11 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 9 Abundance #111070:1-Buten-3-yne, 1-chioro-, (Z)- 51 86 3.40 3.60 3.80 4.00 4.20 m/z 36.10 18.26% 5000

60 0 TI0100110000000mmpmmgut -mppmmmppt ............... mfz~> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.40 3.60 3.80 4.00 4.20

LBA.D 052202.M Mon Jun 03 11:28:11 2002 Page 8

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